using $x^3+y^3 = (x+y)^3 - 3xy(x+y)$ and $a= \sin^2 a$ and $y = \cos^2 a$
we get $\sin^6 a+\cos^6 a = 1- 3\sin^2a \cos^2 a = .25$
or $3\sin^2a \cos^2 a= .75$
or $4\sin^2a \cos^2 a= 1$
or $\sin^22 a = 1$
or $\sin 2a = \pm1$
or $2a = n\pi\pm \frac{\pi}{2}$
hence $a= \frac{ n\pi\pm \frac{\pi}{2}}{2}$
or $a = (\frac{n}{2}\pm\frac{1}{4})\pi$
because we are taking $\pm{1/4}$ from integer and half integer we can simplify above as
$a = (n\pm\frac{1}{4})\pi$