Solving for Eigenvalues in a Finite Square Well with Both Walls Finite

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SUMMARY

The eigenvalue solutions for a finite square well with both walls finite are defined by the equation tan(kl) = 2αk / (k² - α²). This equation is derived from the boundary conditions applied to the time-independent Schrödinger equation, where the general solution is u(x) = A sin(kx) for the region between 0 and L. The boundary conditions lead to the relationships k cot(kL) = -α and k cot(kL/2) = α, which are essential for solving the problem. The discussion emphasizes the importance of continuity in the wave function and its derivative at the boundaries of the well.

PREREQUISITES
  • Understanding of the Time Independent Schrödinger Equation
  • Familiarity with boundary conditions in quantum mechanics
  • Knowledge of trigonometric functions, specifically cotangent and tangent
  • Basic concepts of quantum mechanics related to potential wells
NEXT STEPS
  • Study the derivation of eigenvalue equations in quantum mechanics
  • Explore the implications of boundary conditions on wave functions
  • Learn about the mathematical properties of trigonometric functions in physics
  • Investigate the behavior of wave functions in different potential well configurations
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focusing on potential wells and eigenvalue problems, will benefit from this discussion.

chris_avfc
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Homework Statement


Already defined that for a 1D well with one finite wall the eigenvalue solutions are given by
k cot(kl) = -α

Show the eigenvalue solutions to well with both walls finite is given by

tan(kl) = 2αk / (k^2 - α^2)

Well is width L (goes from 0 to L) with height V_0

Homework Equations



k cot(kl) = -α

tan(kl) = 2αk / (k^2 - α^2)

Time Independent Schrödinger Equation.

The Attempt at a Solution



I will explain briefly as there is a lot of equations and it will look a mess, I can always upload a picture of my work if needs be.

General Solution:
u(x) = Ce^-αx + De^αx

For x < 0
C = 0, so exponential doesn't go to ∞.
For x > L
D = 0 so exponential doesn't go to ∞.

Using boundary conditions where the function and it's derivative must be continuous
With the solution between 0 and L being

u(x) = A sin(kx)

Substituting in L for x

A sin(kL) = Ce^-αL
Ak cos(kL) = -αCe^-αL

Dividing the second by the first

k cot(kL) = -α (As given in question)

This breaks down when substituting in 0 for x.

A sin(k0) = De^α0
Ak cos(k0) = αDe^α0
0 = αD

I thought about changing the coordinates so the well runs from -L/2 to L/2, but that just appears to give

k cot(kL/2) = -α

And

k cot(kl/2) = α

I was/am looking in one textbook, and that manages to get it down to

k tan (kL/2)= α
k cot (kL/2)= -α

Still not what I need, but might be closer?
 
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Guess nobody can help then. :(
 

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