Spectrophotometry of chromium salt

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In summary, the 575 nm wavelength is used in spectrophotometry of Potassium dioxalatodiaquochromate (III) dihydrate because it has the highest absorption coefficient, making it the most sensitive choice for measuring the substance's absorption. This is typically determined through experimentation, rather than a theoretical reasoning based on complementary colors.
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aaku516
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Homework Statement


Why is 575 nm wavelength used in spectrophotometry of Potassium dioxalatodiaquochromate (III) dihydrate?


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The Attempt at a Solution


Cannot find discrete reasoning!
 
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  • #2
I would start searching for the full absorption spectrum.
 
  • #3
Yes I did search for it and found a page --> http://science.herograw.net/chem333l/CHEM333L-UV_Vis.pdf . But their reasoning is purely based on errors on absorption that were determined when using a variety of wavelengths. But I was wondering if there was a theoretical reason somehow including the concept complementary colors?
 
  • #4
I have never heard about using complementary colors for the wavelength selection. If you have a single substance you will usually select wavelength for which the absorption coefficient is the highest, as this gives the best sensitivity. If there are interfering substances, you will select wavelengths for which differences in absorption coefficients between your substance and the impurities are the highest.
 
  • #5


The wavelength of 575 nm is used in spectrophotometry of Potassium dioxalatodiaquochromate (III) dihydrate because it corresponds to the maximum absorbance of the compound. This means that at this specific wavelength, the compound absorbs the most light, making it easier to detect and measure. By using this wavelength, the spectrophotometer can accurately determine the concentration of the compound in a sample. Additionally, using a specific wavelength allows for consistency and reproducibility in measurements, making it a standard wavelength for this particular compound.
 

1. What is spectrophotometry and how is it used to measure chromium salt?

Spectrophotometry is a technique used to measure the amount of light absorbed or transmitted by a substance. In the case of chromium salt, a spectrophotometer is used to measure the amount of light absorbed by the salt at a specific wavelength, which can then be used to determine the concentration of the salt in a solution.

2. Why is spectrophotometry the preferred method for measuring chromium salt?

Spectrophotometry is the preferred method for measuring chromium salt because it is a highly accurate and sensitive technique. It allows for precise measurements of even small concentrations of the salt, making it ideal for use in scientific research and industrial applications.

3. What are the benefits of using a spectrophotometer for chromium salt analysis?

Using a spectrophotometer for chromium salt analysis offers several benefits. It is a non-destructive technique, meaning the sample can be reused for further analysis. It also provides a quick and efficient analysis, with results available in a matter of seconds. Additionally, it can be used for both qualitative and quantitative analysis of chromium salt.

4. Can spectrophotometry be used to detect impurities in chromium salt?

Yes, spectrophotometry can be used to detect impurities in chromium salt. By measuring the absorption of light at different wavelengths, impurities can be identified and quantified. This allows for the purity of the chromium salt to be determined, which is important for applications where high purity is required.

5. Are there any limitations to using spectrophotometry for chromium salt analysis?

While spectrophotometry is a highly accurate and sensitive technique, there are some limitations to its use for chromium salt analysis. It is important to ensure that the spectrophotometer is properly calibrated and that the sample is prepared correctly to avoid any errors in the results. Additionally, the technique may not be suitable for samples that are highly colored or turbid, as this can interfere with the measurement of light absorption.

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