Spectroscopy and Russell-Saunders coupling

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SUMMARY

The discussion centers on the interpretation of angular momentum in quantum mechanics, specifically regarding closed subshells and Russell-Saunders coupling. It establishes that while the sum of the magnetic quantum numbers (M_L) for electrons in a closed subshell equals zero, this does not imply that the total angular momentum (L) must also be zero. The participant questions the conclusion drawn in their spectroscopy course, emphasizing that knowing M_L alone does not determine the magnitude of L, which can take on values greater than zero, such as L=1.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly angular momentum.
  • Familiarity with quantum numbers, including m_l and L.
  • Knowledge of Russell-Saunders coupling and its implications in atomic structure.
  • Basic concepts of spectroscopy and electron configurations in atoms.
NEXT STEPS
  • Study the mathematical formulation of angular momentum in quantum mechanics.
  • Explore the implications of Russell-Saunders coupling on atomic states.
  • Learn about the addition of angular momentum and its rules in quantum systems.
  • Investigate the relationship between magnetic quantum numbers and total angular momentum in various atomic configurations.
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Students and professionals in physics, particularly those specializing in quantum mechanics, atomic physics, and spectroscopy, will benefit from this discussion.

Amok
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So, this has been bugging me for years (seriously). So my spectroscopy course says the following:

1) In an atom, for a closed subshell, for each electron possesing an [tex]m_l[/tex] quantum number there is another electron possesing [tex]-m_l[/tex], which means that the sum [tex]M_L = \sum {m_l} = 0[/tex]. I have no problem with this, it is pretty obvious. However, my course concludes from this that the magnitude of the total angular momentum (magnitude of L) has to be 0! How can they know that, I would only conclude that the projection of the vector L on the z-axis is 0 and nothing else!

2)The same rule applies to spin angular momenta.

I guess my more general doubt is how to determine the possible values for the magnitude of L (the sum of angular momenta of electrons) by knowing only the magnitudes of the angular momentum of each individual electron as well as the projection of angular momenta of electron on the z-axis.
 
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If, for example, ##L=1##, then there must exist states with ##M_L= \pm 1## in addition to ##M_L=0##.

If only ##M_L=0## can exist, then the only total angular momentum possible is ##L=0##.
 

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