Mr-R said:
Polar coor. is a curved system which can be used on a flat Euclidean space. And spherical coor. is a curved system which can be used on a 3D Euclidean space. Right?
For the appropriate definition of "curved", this is right, yes. But note that that definition doesn't generalize: it only works if the underlying space is Euclidean. If you are trying to use these coordinates on a non-Euclidean underlying space, they may not be curved in terms of that underlying space. See below.
Mr-R said:
Lets say that I live on a sphere. So it has a curved surface. I want to describe some points on it. I choose to use spherical coordinates. So did I just use a flat metric to describe a curved surface?
No. You used coordinates that, on that particular surface, happen to be "flat"--more precisely, partially flat (see below)--but the coordinates are not the same as the metric. The metric is still curved.
I said "partially flat" above because if we use, say, latitude and longitude as coordinates on the Earth's surface, lines of constant longitude are geodesics (the closest thing to "straight lines" on the sphere's surface, i.e., the equivalent of "flat", non-curved lines on a plane), lines of constant latitude are not (except for the equator). So we can't say that the coordinates are entirely flat or entirely curved. (Note, btw, that the same is true for polar coordinates on a plane or spherical coordinates in 3-D Euclidean space: some coordinate lines are straight and some are curved.)
Also, it's worth nothing that the term "spherical coordinates" on the surface of a 2-sphere is actually ambiguous: it can mean something like latitude and longitude, which is what I assumed you meant above, but it can also mean a system of coordinates something like polar coordinates, where we pick a particular point as the "origin" (say the North Pole), and use "radius" from that point (i.e., distance along a line of longitude from the North Pole) and "angle" (which line of longitude) as our coordinates. The coordinate lines will be the same as for latitude and longitude, but the actual coordinate values will be somewhat different. This kind of system, with one dimension added (so that we have a radius and two angular coordinates, like spherical coordinates), is commonly used in astronomy to describe the universe as a whole.