Spin-1 particle in uniaxial crystal field

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cscott
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Homework Statement



[tex]H = -D(S^z)^2[/tex] for cases D>0, D<0, where D<0 should remove the degeneracy in the ground state.

Homework Equations



[tex]H = -D(S^z)^2 = -D\hbar^2 (1 0 0; 0 0 0; 0 0 1)[/tex]
(`;' separates rows)

[tex]det(H-1E)= 0[/tex], or by inspection...

The Attempt at a Solution



I get, for D>0,

[itex]E_1 = -D \hbar^2[/itex], [itex]\psi_1=(1,0,0)[/itex]
[itex]E_2 = -D \hbar^2[/itex], [itex]\psi_2=(0,0,1)[/itex]
[itex]E_3 = 0[/itex], [itex]\psi_3=(0,1,0)[/itex]

So I get a degeneracy in the ground state, However I don't see how D<0 removes it.
 
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For D<0 the ground state will be with m=0, i.e. the spin is perpendicular to the z-axis, whereas both m=+1 and -1 will have the same but larger energy.
 
Thanks! I definitely thought about that too hard haha