Statistical Mechanics Occupation number

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SUMMARY

The discussion centers on the calculation of macrostates and microstates in statistical mechanics, specifically regarding bosons and their occupancy in non-degenerate energy states. The user initially presented a calculation of microstates that was deemed incorrect by other participants. Ultimately, the user resolved their confusion by correctly identifying the macrostates as (0,3), (1,2), (2,1), and (3,0), and utilized the Bose-Einstein distribution function to determine the corresponding microstates. This highlights the importance of understanding the definitions and calculations related to macrostates and microstates in statistical mechanics.

PREREQUISITES
  • Understanding of bosons and their properties in quantum mechanics.
  • Familiarity with the concepts of macrostates and microstates.
  • Knowledge of the Bose-Einstein distribution function.
  • Basic principles of statistical mechanics.
NEXT STEPS
  • Study the derivation and applications of the Bose-Einstein distribution function.
  • Explore the differences between bosons and fermions, particularly regarding occupancy rules.
  • Learn about the implications of degeneracy in energy states in statistical mechanics.
  • Investigate advanced topics in statistical mechanics, such as phase transitions and ensemble theory.
USEFUL FOR

Students and researchers in physics, particularly those focused on statistical mechanics, quantum mechanics, and thermodynamics, will benefit from this discussion.

tanaygupta2000
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Homework Statement
Three bosons are to be filled in two energy states with degeneracies 3 and 4 respectively.
(1.) List all the macrostates.
(2.) How many microstates does this 3-particle system has?
(3.) Which macrostate is the most probable one?
Relevant Equations
Partition function, Z = ∑g(j)exp(-E(j)/kT)
Upto now I've only dealt with the problems regarding non - degenerate energy states.
Since bosons do not follow Pauli's Exclusion Principle, three bosons can be filled in two energy states (say E1 and E2) as:
E1
E2
1 boson​
2 bosons​
2 bosons​
1 boson​
3 bosons​
0 bosons​
0 bosons​
3 bosons​

so that there are 2 macrostates (corresponding to levels E1 and E2) and 4 microstates (corresponding to 4 possibilities).
Also the probability of occurrence of
  • I Possibility = 3!/2! = 3
  • II Possibility = 3!/2! = 3
  • III Possibility = 3!/3! = 1
  • IV Possibility = 3!/0! = 6
Is this correct way of dealing with this problem?
I do not understand the meaning behind the given degeneracies of energy states.
 
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tanaygupta2000 said:
so that there are 2 macrostates
Really? How do you define a macrostate?

Your calculation of microstates also appears to be wrong. So define that also.
 
DrClaude said:
Really? How do you define a macrostate?

Your calculation of microstates also appears to be wrong. So define that also.
My problem has been solved. I got correct macrostates (0,3), (1,2), (2,1), (3,0), and microstates corresponding to each one of them using BE distribution function.
Thank You !
 
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