Statistical mechanics/Thermodynamics two spin-1/2 subsystem

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SUMMARY

The discussion focuses on the thermodynamic behavior of two spin-1/2 subsystems with identical magnetic moments in a constant magnetic field. The initial energies of the subsystems are defined as UiA = μB(2a - NA) and UiB = μB(2b - NB). The equilibrium condition is established as a0/NA = b0/NB, indicating that both subsystems achieve equal magnetization when energy is exchanged. Participants emphasize the importance of multiplicity and entropy in determining the most probable macrostate for equilibrium.

PREREQUISITES
  • Understanding of statistical mechanics concepts, particularly multiplicity (Ω(N,n)).
  • Familiarity with thermodynamic equilibrium and energy exchange principles.
  • Knowledge of entropy and its role in determining system states.
  • Basic grasp of magnetic moments and their behavior in magnetic fields.
NEXT STEPS
  • Study the concept of multiplicity in statistical mechanics, focusing on Ω(N,n) calculations.
  • Learn about the relationship between entropy and equilibrium states in thermodynamic systems.
  • Explore the implications of energy conservation in systems with multiple subsystems.
  • Investigate the behavior of magnetic moments in varying magnetic fields and their statistical distributions.
USEFUL FOR

This discussion is beneficial for students and researchers in physics, particularly those studying statistical mechanics, thermodynamics, and magnetism. It is especially relevant for anyone working on problems involving spin systems and energy exchange.

S_Flaherty
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Homework Statement


Consider two spin-1/2 subsystems with identical magnetic moments (μ) in equal fields (B). The first subsystem has a total of NA spins with initially "a" having magnetic moments pointing against the field and (NA - a) pointing along the field, so that its initial energy is UiA = μB(a - (NA - a) = μB(2a - NA). The second subsystem has a total of NB spins with "b" having moments initially pointing against the field so that its initial energy is UiB = μB(2b - NB). Now suppose that the two subsystems are brought together so that they can exchange energy. Assume that B = constant and a, b, NA, NB >> 1. Show that in equilibrium, a0/NA = b0/NB, and this implies that the two subsystems will have the same "magnetization," i.e. total magnetic moment/spin.


Homework Equations


I'm not really sure what equations are useful in this case because I'm having trouble understanding what I need to be doing. I think I need to use multiplicity so
Ω(N,n) = N!/(n!(N-n)!)


The Attempt at a Solution


I think that I have to first figure out the most probable macrostate because that is where the systems would be in equilibrium(?). So do I go along the lines of solving Ω(NA, a) and Ω(NB, b)? I don't even know if that makes sense or what a0 and b0 represent in this question.
 
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You're going in the right direction. Have you seen entropy yet? If so, can you express the conditions for equilibrium in terms of S and U?

My guess is that a0 and b0 are the number of spins pointing against the field at equilibrium.
 
S_Flaherty said:
I think that I have to first figure out the most probable macrostate because that is where the systems would be in equilibrium(?). So do I go along the lines of solving Ω(NA, a) and Ω(NB, b)? I don't even know if that makes sense or what a0 and b0 represent in this question.
exactly. But also, don't forget to constrain the total energy! And yeah, as DrClaude says, the a0 and b0 seem to simply be a and b once equilibrium is achieved.
 

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