Stern Gerlach term in the Pauli Equation

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SUMMARY

The Stern Gerlach term in the Pauli equation arises from the application of the Pauli vector identity, specifically when manipulating the momentum operator and vector potential. The discussion highlights that the term is not zero due to the non-commuting nature of the momentum operator with the vector potential, leading to the expression -eħσ·B. The key identity used is that the cross product of the momentum operator and vector potential does not equal zero, which is crucial for deriving the Stern Gerlach term. The conclusion emphasizes the importance of recognizing that vector calculus identities do not always hold for vector operators.

PREREQUISITES
  • Understanding of the Pauli equation and its components
  • Familiarity with vector calculus and vector operators
  • Knowledge of quantum mechanics, particularly the role of momentum and vector potentials
  • Proficiency in manipulating complex algebraic expressions involving operators
NEXT STEPS
  • Study the derivation of the Pauli equation in quantum mechanics
  • Learn about the implications of non-commuting operators in quantum mechanics
  • Explore the mathematical properties of vector calculus in the context of quantum mechanics
  • Investigate the physical significance of the Stern Gerlach experiment and its relation to spin
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Quantum physicists, graduate students in physics, and researchers focusing on quantum mechanics and operator algebra will benefit from this discussion.

Mantella
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Where does the Stern Gerlach term in the Pauli equation come from? Taken from http://en.wikipedia.org/wiki/Pauli_equation. Following wikipedia's steps the Stern Gerlach term pops out when you apply the Pauli vector identity. I don't understand this step. It seems as if there should be no Stern Gerlach term.

Here are my steps starting with the Pauli vector identity,
[itex](\boldsymbol{\sigma} \cdot \boldsymbol{a})(\boldsymbol{\sigma} \cdot \boldsymbol{b}) = \boldsymbol{a} \cdot \boldsymbol{b} + i\boldsymbol{\sigma} \cdot (\boldsymbol{a} \times \boldsymbol{b})[/itex]

[itex](\boldsymbol{\sigma} \cdot (\boldsymbol{p} - e\boldsymbol{A}))^2 = (\boldsymbol{\sigma} \cdot (\boldsymbol{p} - e\boldsymbol{A}))(\boldsymbol{\sigma} \cdot (\boldsymbol{p} - e\boldsymbol{A})) = (\boldsymbol{p} - e\boldsymbol{A})^2 + i\boldsymbol{\sigma} \cdot ((\boldsymbol{p} - e\boldsymbol{A}) \times (\boldsymbol{p} - e\boldsymbol{A}))[/itex]

Shouldn't

[itex]\boldsymbol{v} \times \boldsymbol{v} = \boldsymbol{0}[/itex]

and

[itex](\boldsymbol{\sigma} \cdot (\boldsymbol{p} - e\boldsymbol{A}))^2 = (\boldsymbol{p} - e\boldsymbol{A})^2[/itex]

I did it out in individual components as well, and came to the same conclusion. What am I missing?
 
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You almost get zero, but you end up with one term because momentum does not commute with the vector potential in general.

[tex] i\boldsymbol{\sigma} \cdot ((\boldsymbol{p} - e\boldsymbol{A}) \times (\boldsymbol{p} - e\boldsymbol{A})) = -\hbar e \epsilon_{jkl}\sigma_j \partial_k A_l = - e \hbar \mathbf{\sigma} \cdot \mathbf{B}[/tex]

I used p = -i hbar ∇. If you look back over your work when you did the calculation by components, you'll probably find the step where you moved the momentum operator past the vector potential.
 
Note that unlike in conventional vector algebra, in this algebra of vector operators
##\mathbf{p}\times \mathbf{A} + \mathbf{A} \times \mathbf{p} \neq 0 ##

$$[\mathbf{A} \times \mathbf{p}]_i = \sum_{jk} \epsilon_{ijk}A_jp_k = \sum_{jk} \epsilon_{ijk}p_kA_j - [p_k, A_j] = \sum_{jk} \epsilon_{ijk}p_kA_j +i\hbar \frac{\partial A_j}{\partial x_k} $$ $$\mathbf{p}\times \mathbf{A} + \mathbf{A} \times \mathbf{p}= i\hbar \nabla \times \mathbf{A} $$

An important takeaway from this is that identities from vector calculus will not always be true for vector operators.

Edit: Have I made a sign error?
 
Last edited:

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