Struggling to understand the concept of spin triplets

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SUMMARY

The discussion clarifies the distinction between spin triplet and singlet states in quantum mechanics, specifically addressing the S=1 state with three projections and the S=0 singlet state. The triplet state, represented by the superposition \(\frac{1}{\sqrt{2}}(|\uparrow\downarrow\rangle + |\downarrow\uparrow\rangle)\), has a total spin expectation value of 1, while the singlet state \(\frac{1}{\sqrt{2}}(|\uparrow\downarrow\rangle - |\downarrow\uparrow\rangle)\) results in a total spin of 0. The expectation values are derived from the total spin operator \(\hat{S^2} = \hat{S_1}^2 + \hat{S_2}^2\), demonstrating the fundamental differences in their rotational properties.

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jack.d
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hi all, can someone please explain to me why the S=1 state has three projections, i don't understand how the up down coupling produces a total spin of 1 in the triplet but then seems to produce a total spin of 0 in the singlet state with the same orientation.

cheers
 
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OK. So, if I'm reading this correctly, your issue is the following:

[tex]\frac{1}{\sqrt{2}}(|\uparrow\downarrow> +|\downarrow\uparrow>)[/tex]

corresponds to a total spin of 1, while

[tex]\frac{1}{\sqrt{2}}(|\uparrow\downarrow> -|\downarrow\uparrow>)[/tex]

corresponds to a total spin expectation value of 0.

The easiest way to see that this is indeed the case is to explicitly work out the expectation value for the total spin operator:

[tex]\hat{S^2}=\hat{S_1}^2+\hat{S_2^2}[/tex]

You should explicitly see that for the first state the expectation value is s=1, while for the second, s=0.

Another, possibly more physical way to think about the problem is the following:

Consider the Singlet State:

Apply the space rotation operator to the state, and you'll notice that it is invariant under all rotations. Only systems with 0 angular momentum can be rotationally invariant, so we know it's spin must be 0.

Similarly, the m=0 triplet state will not be rotationally invariant, so we know it has some angular momentum.

Thus, even though the states "look" similar, they have very different rotational properties, thus different spin values.
 

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