Total spin of triplet and singlet states

In summary, the total spins for the states ↑↓+↓↑ and ↑↓-↓↑ are 1 and 0, respectively. This can be determined by applying the total spin operator to the states and by using the theorem of the addition of angular momenta. The z component of the resultant state's representation can also be found by summing the z components of the individual states in the individual spin state basis. Recommended readings for further understanding are Chapter 4 of Introduction to QM by Griffith and Chapter 3 of Modern QM by Sakurai, or MIT's opencourse material on quantum physics.
  • #1
K448
3
0
I'm a litte confused about spin triplet and singlet states. How do we know that for ↑↓+↓↑ the total spin S is 1, and for ↑↓-↓↑ the total spin S is 0?
Also, how is total ms computed for these two states? (I understand that they are both 0, but not sure where that comes from)

Thank you very much for the help!
 
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  • #2
K448 said:
How do we know that for ↑↓+↓↑ the total spin S is 1, and for ↑↓-↓↑ the total spin S is 0?
Apply the (squared) total spin operator ##\mathbf{S}^2 = (\mathbf{S_1}+\mathbf{S_2})^2## to those states.
K448 said:
Also, how is total ms computed for these two states
Apply the operator ##S_z = S_{1z} + S_{2z}## to those states. Alternatively, upon following the theorem of the addition of angular momenta, you will find that the z component of the resultant spin state is equal to the sum of the z components of the individual states appearing in the resultant state's representation in the individual spin state basis.
 
  • #3
blue_leaf77 said:
Apply the (squared) total spin operator ##\mathbf{S}^2 = (\mathbf{S_1}+\mathbf{S_2})^2## to those states.

Apply the operator ##S_z = S_{1z} + S_{2z}## to those states. Alternatively, upon following the theorem of the addition of angular momenta, you will find that the z component of the resultant spin state is equal to the sum of the z components of the individual states appearing in the resultant state's representation in the individual spin state basis.
Thank you very much! I realize I never learned the total spin operator... Is there a recommended reading about this?
 
  • #5
blue_leaf77 said:
Introduction to QM by Griffith chapter 4 or Modern QM by Sakurai chapter 3. The latter is more advanced than the former but especially on the addition of angular momenta and it's in fact my favorite QM book, I found it still easy to understand. Alternatively MIT's opencourse material will also do http://ocw.mit.edu/courses/physics/...all-2013/lecture-notes/MIT8_05F13_Chap_10.pdf
Thank you! :)
 
1.

What is the difference between the total spin of triplet and singlet states?

The total spin of a state refers to the sum of the spin of all the particles in that state. In a triplet state, the total spin is equal to 1, while in a singlet state, the total spin is equal to 0. This means that triplet states have spin quantum numbers of 1, 0, or -1, while singlet states have a spin quantum number of 0.

2.

How do triplet and singlet states differ in terms of their electron spin configurations?

In a triplet state, the electron spins are parallel to each other, meaning they have the same direction. In a singlet state, the electron spins are antiparallel, meaning they have opposite directions. This difference in spin configurations is what leads to the difference in total spin between the two states.

3.

Why are triplet and singlet states important in quantum mechanics?

Triplet and singlet states are important in quantum mechanics because they play a crucial role in determining the properties of molecules and their chemical reactions. These states are also used in various experimental techniques, such as electron spin resonance, to study the electronic properties of materials.

4.

Can triplet and singlet states be interconverted?

Yes, triplet and singlet states can be interconverted through a process called spin flipping. This occurs when the spin orientation of an electron changes, resulting in a change of state from triplet to singlet or vice versa.

5.

How are triplet and singlet states related to the Pauli exclusion principle?

The Pauli exclusion principle states that no two electrons in an atom can have the same set of quantum numbers. In the case of triplet and singlet states, this principle is evident in the fact that the spin quantum numbers for each state are different, resulting in different electronic configurations. This principle also explains why only two electrons can occupy each orbital, as they must have opposite spins to avoid violating the exclusion principle.

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