You can put it also a bit differently and say a superselection rule constrains the possible superpositions of states. One example is the "spin selection rule". In usual quantum theory you cannot make superpositions of a state with half-integer and integer spin. Suppose you do so, i.e., having, e.g., ##s_1=1/2## and ##s_2=0## and consider the state
$$|\psi \rangle=|1/2,-1/2 \rangle+|1,-1 \rangle,$$
then the rotation around the ##z## axis by ##2 \pi## does not give ##\exp(\mathrm{i} \varphi) |\psi \rangle## for any real ##\varphi##.
Then of course you have a restriction on the possible operators, representing observables, particularly the Hamiltonian: Such an operator must not mix any half-integer spin state with an integer-spin state and vice versa.