Superselection rules dictate that not all Hermitian operators can be treated as physical observables due to imposed constraints on the structure of observables in quantum mechanics. These rules arise from the geometry of spacetime, which requires that certain transformations, like full rotations, do not alter the system's properties. Consequently, fermionic and bosonic states become out of phase after such transformations, leading to the conclusion that observable operators must be confined to separate superselection sectors. Operators that cannot be decomposed into these sectors are deemed non-observable, as they would violate the constraints imposed by superselection rules. This fundamentally restricts the types of superpositions allowed in quantum states, particularly affecting the Hamiltonian and other observable operators.