The dirac equation of the hydrogen atom

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Discussion Overview

The discussion focuses on the application of the Dirac equation to the hydrogen atom, specifically examining the potential used in this context. Participants explore whether the potential should remain the same as in the non-relativistic Schrödinger equation or if modifications are necessary.

Discussion Character

  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether the potential for the Dirac equation of the hydrogen atom should be modified from the 1/r potential used in the Schrödinger equation.
  • Another participant asserts that in non-relativistic quantum mechanics, the same 1/r potential is used, prompting a request for further clarification.
  • A participant speculates that since the time-independent solution is in vector form, a potential in the form of a vector field might need to be considered, though they express uncertainty about this idea.
  • One participant suggests choosing a gauge where the vector potential A = 0, which would leave the Coulomb 1/r potential intact, and describes a method for solving the Dirac equation using spherical coordinates and confluent hypergeometric functions.

Areas of Agreement / Disagreement

Participants exhibit some agreement on the use of the 1/r potential in non-relativistic quantum mechanics, but there is uncertainty regarding the necessity of modifications for the Dirac equation. Multiple viewpoints on the potential's form and implications remain unresolved.

Contextual Notes

Some assumptions about the nature of the vector potential and its implications for the Dirac equation are not fully explored, and the discussion does not resolve the question of whether modifications to the potential are necessary.

Kamper
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What potential would one use when evaluating the Dirac equation of the hydrogen atom? Would it simply be in the form used when examining the hydrogen atom-Schrödinger equation or does it need modification?
 
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In non-rel. QM one starts with the same 1/r potential. What else do you have in mind?
 
tom.stoer said:
In non-rel. QM one starts with the same 1/r potential. What else do you have in mind?

I was just wondering that since the time-independent part of the solution is in vector form you might have to consider a potential in the form of a vector field. But maybe i´m wrong?
 
Thanks for the reply by the way!
 
I was just wondering that since the time-independent part of the solution is in vector form you might have to consider a potential in the form of a vector field. But maybe i´m wrong?
Choose a gauge in which the vector potential A = 0, leaving just the Coulomb 1/r potential. Separate variables in spherical coordinates as usual, and you'll find that the four components of the Dirac spinor can be written in terms of two radial functions, leding to recursion relations, etc, etc, and solved by confluent hypergeometric functions.
 
Bill_K said:
Choose a gauge in which the vector potential A = 0, leaving just the Coulomb 1/r potential. Separate variables in spherical coordinates as usual, and you'll find that the four components of the Dirac spinor can be written in terms of two radial functions, leding to recursion relations, etc, etc, and solved by confluent hypergeometric functions.

Ill try that then. Thank you!
 

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