Thermal decomposition of calcium carbonate ?

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SUMMARY

The thermal decomposition of calcium carbonate (CaCO3) occurs at approximately 825°C, resulting in the formation of calcium oxide (CaO) and the release of carbon dioxide (CO2). Decomposition does not occur at temperatures below 825°C, as this reaction requires conditions where the Gibbs free energy is zero. The standard state for this reaction assumes a partial pressure of CO2 at 1 atm. The cement and lime industries rely on this temperature threshold for effective processing.

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  • Understanding of thermal decomposition reactions
  • Familiarity with Gibbs free energy concepts
  • Knowledge of standard state conditions in chemistry
  • Basic principles of calcination processes
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  • Research the principles of Gibbs free energy and its role in chemical reactions
  • Explore the calcination process in the cement industry
  • Study the thermal properties of calcium carbonate and its decomposition kinetics
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Chemists, materials scientists, and professionals in the cement and lime industries will benefit from this discussion, particularly those interested in thermal processing and chemical reactions involving calcium carbonate.

makky2008
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In general, we heat CaCO3 to temperature of approximately 825°C it decomposes into calcium oxide and liberates carbon dioxide gas:

CaCO3 →825°C→ CaO + CO2

Is it possible to heat the calcium carbonate at temperatures below 825 degrees Celsius, so the decomposition into calcium oxide.
 
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makky2008 said:
Is it possible to heat the calcium carbonate at temperatures below 825 degrees Celsius

Sure, you can heat it to any temperature you want :wink:

so the decomposition into calcium oxide.

Please translate into English, no idea what you were trying to ask.
 
If the OP is asking if calcium carbonate will decompose at a temp. below 825 C, the answer is no.

See this article:

http://en.wikipedia.org/wiki/Calcination

This type of decomposition occurs only at temperatures above which the Gibbs free energy is zero. Certainly, if this reaction could occur at lower temps., the cement and lime industry would be all over it.
 
This is slightly more complicated, 825 C is probably for a standard state, when the partial pressure of CO2 is expected to be 1 atm.
 
Thank you very much Mr.Borek and SteamKing.
 

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