Thermal decomposition of calcium carbonate ?

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Discussion Overview

The discussion revolves around the thermal decomposition of calcium carbonate (CaCO3), specifically whether it can decompose into calcium oxide (CaO) at temperatures below the commonly cited threshold of 825°C. The scope includes theoretical and conceptual considerations regarding the conditions necessary for this reaction to occur.

Discussion Character

  • Debate/contested
  • Technical explanation

Main Points Raised

  • Some participants assert that heating CaCO3 to approximately 825°C is necessary for its decomposition into CaO and CO2.
  • One participant humorously suggests that it is possible to heat calcium carbonate to any temperature, questioning the clarity of the original inquiry.
  • Another participant firmly states that CaCO3 will not decompose at temperatures below 825°C, referencing Gibbs free energy considerations.
  • A later reply adds that the 825°C threshold may be specific to standard conditions, particularly when the partial pressure of CO2 is at 1 atm.

Areas of Agreement / Disagreement

Participants express disagreement regarding the possibility of decomposition at temperatures below 825°C, with some asserting it is not feasible while others provide humorous or clarifying remarks. The discussion remains unresolved regarding the implications of varying conditions on the decomposition process.

Contextual Notes

There are limitations regarding assumptions about standard states and the specific conditions under which the decomposition occurs, as well as the dependence on the partial pressure of CO2.

makky2008
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In general, we heat CaCO3 to temperature of approximately 825°C it decomposes into calcium oxide and liberates carbon dioxide gas:

CaCO3 →825°C→ CaO + CO2

Is it possible to heat the calcium carbonate at temperatures below 825 degrees Celsius, so the decomposition into calcium oxide.
 
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makky2008 said:
Is it possible to heat the calcium carbonate at temperatures below 825 degrees Celsius

Sure, you can heat it to any temperature you want :wink:

so the decomposition into calcium oxide.

Please translate into English, no idea what you were trying to ask.
 
If the OP is asking if calcium carbonate will decompose at a temp. below 825 C, the answer is no.

See this article:

http://en.wikipedia.org/wiki/Calcination

This type of decomposition occurs only at temperatures above which the Gibbs free energy is zero. Certainly, if this reaction could occur at lower temps., the cement and lime industry would be all over it.
 
This is slightly more complicated, 825 C is probably for a standard state, when the partial pressure of CO2 is expected to be 1 atm.
 
Thank you very much Mr.Borek and SteamKing.
 

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