Thermochemistry: Heat of a Solution

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SUMMARY

The heat of solution for potassium acetate (KC2H3O2) in water is -15.3 kJ/mol, indicating that the dissolution process is endothermic. When 12.7 g of KC2H3O2 is dissolved in 525 mL of water at an initial temperature of 22.2 °C, the final temperature of the solution is calculated to be approximately 21.32 °C. The calculations involve determining the number of moles of KC2H3O2, converting the heat of solution to joules, and applying the formula deltaE = C * deltaT. The final temperature is lower than the initial due to the absorption of heat during the dissolution process.

PREREQUISITES
  • Understanding of thermochemistry concepts, specifically heat of solution.
  • Knowledge of molar mass calculations and conversions.
  • Familiarity with specific heat capacity, particularly for water (4.18 J/g°C).
  • Ability to manipulate and solve equations involving deltaE and deltaT.
NEXT STEPS
  • Study the principles of endothermic and exothermic reactions in thermochemistry.
  • Learn how to calculate heat transfer in solutions using calorimetry.
  • Explore the concept of molarity and its applications in solution chemistry.
  • Investigate the effects of solute concentration on the thermal properties of solutions.
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Chemistry students, educators, and professionals involved in thermochemical calculations and solution chemistry will benefit from this discussion.

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Homework Statement



The heat of solution of potassium acetate (KC2H3O2) in water is -15.3 kJ/mol.
If 12.7 g of KC2H3O2(s) is dissolved in 525 mL of water that is initially at 22.2 °C, what will be the final temperature (in degrees celsius) of the resulting aqueous solution?

Homework Equations



Unsure. I used:

deltaE = C * deltaT

The Attempt at a Solution



First calculating moles: 12.7g / 98.1417g/mol = 0.1294047281 mol

Secondly, calculating kJ per mole: 0.1294047281 mol * -15.3kJ/mol = -1.97989234kJ -> -1979.89234 J

Third, sub into equation: -1979.89234J / (4.18 J/g * 537.7g) = deltaT

deltaT = -0.880897256
22.2 degrees - 0.880897256 = 21.31910274

The answer is incorrect. I use an online homework system and the following answers are incorrect:

21.3
21.2
 
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If heat of solution is negative, does it mean heat is produced, or absorbed? And should the final temp be higher or lower than initial?

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methods
 

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