Time-Dependent Degenerate Pertubation Theory for Spin System

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SUMMARY

The discussion focuses on applying degenerate perturbation theory to a spin system described by the Hamiltonian H = ASZ + B(SX - SY). The Hamiltonian is represented in the SZ basis as a 3x3 matrix: ℏ2[(A,0,B; 0,0,0; B,0,A)]. Participants clarify that the perturbation should be treated with B as a small parameter, leading to eigenvalues of 0, A+B, and A-B. The correct approach involves diagonalizing the perturbation in the 2-dimensional subspace corresponding to the degenerate eigenvalue A of the unperturbed Hamiltonian.

PREREQUISITES
  • Understanding of Spin Hamiltonians and their representations
  • Familiarity with degenerate perturbation theory
  • Knowledge of Pauli matrices and their dimensionality
  • Basic concepts of quantum mechanics and eigenvalue problems
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  • Review the principles of degenerate perturbation theory in quantum mechanics
  • Study the derivation and application of Spin Hamiltonians
  • Learn about the diagonalization of matrices in quantum systems
  • Explore the implications of perturbation theory on eigenvalues and eigenstates
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Students and researchers in quantum mechanics, particularly those studying spin systems and perturbation theory, will benefit from this discussion.

jcharles513
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Homework Statement


Consider the so-called Spin Hamiltonian
H=AS2Z+B(S2X-S2Y)

for a system of spin 1. Show that the Hamiltonian in the SZ basis is the 3x3 matrix:

\hbar2*[(A,0,B; 0,0,0; B,0,A)].Find the eigenvalues using degenerate pertubation theory.

Homework Equations


Spin Pauli Matrices

The Attempt at a Solution



I don't know where to start with this since the Pauli Matrices I know are 2x2 matrices. How did the Hamiltonian become a 3x3. What am I missing? Can someone get me started?
 
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See here where ##\hbar## has been set equal to 1.
 
Thank you. That makes sense. I guess I wasn't searching for the right thing in google. I may have more questions after that but this gets me started.
 
Degen. Perturb.

TSny said:
See here where ##\hbar## has been set equal to 1.


I'm confused about how to use degenerate perturbation on this system. My understanding of degenerate perturbation is shaky. I know that I need to take a subspace of this matrix that has the degeneracy and then transform the perturbation of that subspace to this new diagonal basis. But I'm not sure what my subspace of this matrix is?
 
I used the 3x3 subspace and got eigenvalues 0,A+B, and A-B. Is this correct? And the correct procedure?
 
I believe those are the correct eigenvalues for the Hamiltonian. Did you get them by finding the exact eigenvalues of the complete Hamiltonian?

I think the exercise is to find eigenvalues using degenerate perturbation theory where you treat B as a small parameter so that the unperturbed Hamiltonian is Ho=ASz2 and the perturbation is V = B(Sx2 - Sy2).
 
I diagonalized the pertubation (B-part) and then added it the A-part. This made it diagonal. I'm not sure if that's the right way to do it or not? If not, can you get me started on the correct method?
 
jcharles513 said:
I diagonalized the pertubation (B-part) and then added it the A-part. This made it diagonal. I'm not sure if that's the right way to do it or not?

In degenerate perturbation theory, you would not diagonalize the B-part in the full 3-dimensional vector space of the hamiltonian. Rather, if you want the perturbation theory correction to the degenerate eigenvalue, A, of the unperturbed Hamiltonian (A-part hamiltonian) you diagonalize the B-part relative to the 2-dimensional space spanned by the degenerate eigenfunctions corresponding to the eigenvalue A of the unperturbed hamiltonian, as explained in standard texts.

In this problem, it turns out that degenerate perturbation theory yields the exact result, and diagonalizing the B-part with respect to the degenerate subspace is equivalent to diagonalizing the entire hamiltonian. But in general that wouldn't be true.

Unless you still have specific questions, I would recommend reviewing degenerate perturbation theory and then coming back with specific questions if you still have any. This is not the place to try to explain the general formalism of degenerate perturbation theory.
 
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