Transition Elements (Naming Substances) check answers

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SUMMARY

The forum discussion focuses on the correct naming of transition metal complexes, specifically four substances. The correct names are: a) Cu(Cl4)2- - tetrachlorocuprate(II) ion; b) Ag(NH3)2+ - diamminesilver(I) ion; c) Cu(NH3)4SO4 - tetraamminecopper(II) sulfate; d) Al(H2O)6Cl3 - hexaaquoaluminum(III) chloride. Key corrections include the use of 'cuprate' for anionic complexes and the omission of 'tri' in 'trichloride' for aluminum complex naming.

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ScrubsFan
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Name the following substances.

a) [Cu(Cl4]2- - tetrachloridecopper(II) ion

b) Ag(NH3)2+ - diamminesilver ion

c) Cu(NH3)4SO4 - tetraamminecoppersulfate (or tetraamminecopper(II) sulfate)

d) Al(H2O)6Cl3 - hexaaquoaluminum(III) trichloride



I have no idea if any of these are right, but someone please help me out if there not.
Thanks.
 
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ScrubsFan said:
Name the following substances.

a) [Cu(Cl4]2- - tetrachloridecopper(II) ion
'chloro', not 'chloride'. Also, since this is an anionic complex, it should be 'cuprate'.

b) Ag(NH3)2+ - diamminesilver ion
Missing oxidation number for silver.

c) Cu(NH3)4SO4 - tetraamminecoppersulfate (or tetraamminecopper(II) sulfate)
Second try is better.

d) Al(H2O)6Cl3 - hexaaquoaluminum(III) trichloride
There should be no "tri" (in trichloride) - just "chloride" is sufficient. The number of chloride ions (ie.: 3) is determined by the oxidation number of the cation and the number of other ligands, if they are charged.
 
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