Trichloroacetic acid: electron density and stability

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Discussion Overview

The discussion centers on the acidity of trichloroacetic acid, specifically exploring the role of electron density and the stabilization of the trichloroacetate anion formed upon dissociation. Participants examine the influence of chlorine atoms on electron distribution and the implications for molecular stability, addressing both theoretical and conceptual aspects.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant notes that the acidity of trichloroacetic acid is attributed to the inductive effect of chlorine atoms, which withdraw electron density from the carboxylate group, stabilizing the resulting anion.
  • Another participant questions why electron density shifts towards chlorine despite oxygen's higher electronegativity, suggesting it may be due to the number of chlorine atoms or the molecular structure.
  • A participant proposes that "stabilized" likely refers to the carboxylic group, prompting further inquiry into the meaning of stability in this context.
  • One participant introduces the concept of resonance as a potential explanation for stabilization.
  • A later reply attempts to clarify that the electronegativity of chlorine draws electrons slightly towards itself, leading to a delocalization that lowers the overall energy of the molecule, thereby increasing stability.

Areas of Agreement / Disagreement

Participants express varying interpretations of the role of electronegativity and resonance in the stabilization of trichloroacetic acid, indicating that multiple competing views remain. The discussion does not reach a consensus on the precise mechanisms at play.

Contextual Notes

Some assumptions regarding the definitions of stability and resonance are not fully explored, and the implications of these concepts in the context of trichloroacetic acid remain unresolved.

nobahar
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"The rather strong acidity of trichloroacetic acid is usually ascribed to the inductive effect of the three chlorine atoms attached to the end of the molecle opposite the acidic proton. Electron density is withdrawn away from the carboxylate group so that the trichloroacetate anion that is formed when the acid dissociates is stabilized." (Skoog, West, Holler & Crouch, 2003)

Isn't oxygen more electronegative than chlorine? So why does the electron density shift in favour of the chlorine atoms? Is it because they outnumber the oxygen atoms, or is it a consequence of the structure (shape) of the molecule?
Also, what is the meaning of the term "stabilized" as used here?
Any input appreciated. I will also continue to search elsewhere; so far it's been to no avail.
 
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The chlorine atoms are replacing hydrogen atoms and chlorine is certainly more electronegative than hydrogen. So, while the chlorine atoms are not going to pull all or most of the electron density away from the oxygen, they will pull some electron density away and the oxygen atom will have less electron density than if the chlorines had not been present.
 
Stabilization most likely refers to the carboxylic group.

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methods
 
Thanks Yggdrasil and Borek. For some reason I took it to mean a change after the proton had departed, but as your explanation makes clear its disucussing the molecule as it stands.

Borek said:
Stabilization most likely refers to the carboxylic group.
What does it mean by stable in this usage? If it was unstable, or less stable, what would this mean?
 
Think resonance.

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methods
 
Thanks Borek.
I think I understand:
The electronegativity of the chlorine atoms draws the electrons, to a small extent, as pointed out above, towards themselves. This 'slight' (?) delocalization of the electrons lowers the overall energy of the molecule; whereas, without the chlorine atoms, the electrons would generally reside in a much smaller area (around the oxygen atoms), and therefore the overall energy of the molecule would be higher, and therefore the molecule would be less stable.
Have I understood resonance correctly? And if so, have I understood it's application here?
Thanks!
 

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