Trouble with picturing the 3-d structures

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SUMMARY

The discussion centers on the challenges of visualizing three-dimensional molecular structures, particularly in relation to hybridization and bond orientation. The user struggles with determining the correct placement of dashes and wedges in molecular diagrams, specifically for molecules like (CH3)3N and [H2COH](+). Key concepts include the understanding of sp2 hybridization for oxygen in [H2COH](+), despite its two lone pairs, and the importance of recognizing sigma and pi bonds in molecular geometry. The conversation emphasizes the necessity of mastering valence-bond theory and hybridization to accurately depict molecular structures.

PREREQUISITES
  • Understanding of hybridization concepts, specifically sp and sp2 hybridization.
  • Familiarity with molecular geometry and electron-domain geometries.
  • Knowledge of sigma and pi bonds in covalent bonding.
  • Ability to interpret Lewis dot structures for complex molecules.
NEXT STEPS
  • Study the principles of valence-bond theory and its application to polyatomic molecules.
  • Learn to draw and interpret molecular structures using dash and wedge notation.
  • Explore the concept of electron-domain geometry and its relation to hybridization.
  • Practice identifying bond types and their implications on molecular rigidity and orientation.
USEFUL FOR

Chemistry students, educators, and anyone seeking to improve their understanding of molecular geometry and hybridization in organic and inorganic chemistry.

tuha
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I know I am overthinking, as always, but for some reason I am just having so much trouble with picturing the 3-d structures (dash/wedge) when solving the problems. My test is tomorrow and I am stuck, I just can't draw them correctly...I get the hybridization, and the angle that will form.
What I don't get is how do you know where to draw a dash or a wedge, and when will the dash be to the upper left corner (extended) versus the lower left? Sometimes they are drawn near each other (dash and wedge going towards the upper left) with the one in the plane going towards the left. How do you determine this? Does it have to do with the bond angles? I tried figuring it out that way, but I still can't get the right figure without looking at the answer for a hint. For example: (CH3)3 N ... I have no idea how to orient my lewis dot to come up with the right three-d...how do you know which of the hydrogens will be off the plane and et.? Is there a simple way of doing this, and what is wrong with the way I am thinking?
Also, for a positive charged [H2COH] (+) molecule, why is the oxygen atom (as it says in my book) sp2? I know the carbon is sp2, but wouldn't trhe oxygen be sp3 because it's bonded to two things, and it also has 2 pairs of lone electrons?
Any help is greatly appreciated.

Thank you for your help in advance!
 
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To extend the ideas of valence-bond theory to polyatomic molecules, we must envision mixing s, p, and sometimes d orbitals to form hybrid orbitals. The process of hybridization leads to hybrid atomic orbitals that have a large lobe directed to overlap with orbitals on another atom to make a bond. Hybrid orbitals can also accommodate nonbonding pairs. A particular mode of hybridization can be associated with each of the five common electron-domain geometries ( trigonal trigonal and ).

Covalent bonds in which the electron density lies along the line connecting the atoms (the internuclear axis) are called sigma bonds. Bonds can also be formed from the sideways overlap of p orbitals. Such a bond is called a pi bond. A double bond, such as that in consists of one bond and one bond; a triple bond, such as that in consists of one and two bonds. The formation of a bond requires that molecules adopt a specific orientation; the two groups in for example, must lie in the same plane. As a result, the presence of bonds introduces rigidity into molecules. In molecules that have multiple bonds and more than one resonance structure, such as the bonds are delocalized; that is, the bonds are spread among several atoms.
 

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