Troubleshooting Home-Made Hofmann Apparatus for Electrolysis

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Discussion Overview

The discussion revolves around troubleshooting a home-made Hofmann apparatus used for electrolysis. Participants explore issues related to gas production at the electrodes, the materials used for electrodes, and the effects of those materials on the electrolysis process.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant reports that only one electrode is producing gas, raising concerns about potential flaws in the setup.
  • Another participant questions the material of the electrodes, suggesting that gas may be evolving on one side while the other electrode could be dissolving.
  • It is noted that the use of copper sheet metal as an electrode may lead to the dissolution of copper, which could affect gas production.
  • A participant explains the oxidation reaction occurring with copper, contrasting it with the expected reaction for water electrolysis.
  • There is a query about suitable alternative electrode materials that would not be prohibitively expensive, with platinum mentioned as a costly option and carbon electrodes suggested as a cheaper alternative.

Areas of Agreement / Disagreement

Participants express differing views on the effectiveness of copper as an electrode material and its impact on the electrolysis process. There is no consensus on the best alternative materials, and the discussion remains unresolved regarding the optimal choice for electrodes.

Contextual Notes

Limitations include assumptions about the behavior of different electrode materials and the specific conditions under which the electrolysis is performed. The discussion does not resolve the effectiveness of carbon electrodes or other alternatives.

Who May Find This Useful

Individuals interested in electrolysis, DIY science projects, or those troubleshooting similar apparatus setups may find this discussion relevant.

pickle_64
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Hi,
i recently constructed a hofmann apparatus at home out of pvc and had some trouble with it. Basically, once it is set up, i only get gas from one electrode, the other does nothing. H2SO4 is used as the electrolyte, and the is 12 volts at 4 amps being put through it, DC. are there any simple flaws i am over looking as i just want to keep the oxygen and hydrogen separate.

thanks, your help is greatly appreciated.
 
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What are your electrodes made off? Prehaps you have evolving gas on one side and you dissolve electrode on the second?
 
copper sheet metal in a coil.
 
Very likely that you are dissolving copper. If so, solution will become bluish.
 
why would this stop the 2nd gas being released?
 
More or less you have

Cu -> Cu2+ + 2e

oxidation reaction instead of

2H2O -> O2 + 4H+ + 4e
 
Thanks for that, i thought copper would have worked and no other site would tell me properly. on the subject, do you know of any suitable metals for use in this situation that wouldn't set me back a heap?
 
Unfortunately the best I can think off is oplatinum - rather expensive. Carbon electrodes will be much cheaper, but don't ask me about details, as I don't know too much about them.
 
thanks for the help
 

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