Understanding Enthalpy of Formation for Water: A Comprehensive Guide

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SUMMARY

The discussion centers on the enthalpy of formation for water, specifically addressing calculations involving water at different temperatures and states. The overall enthalpy equation includes the enthalpy of formation, enthalpy of water at 1800K, and enthalpy of water at 298K. It is established that for steam calculations, one should utilize steam tables, particularly under low pressure combustion conditions at 1 atm. The enthalpy of formation for water is confirmed to be relevant for both gas and liquid states, depending on the context of the calculations.

PREREQUISITES
  • Understanding of enthalpy and thermodynamic principles
  • Familiarity with steam tables and their applications
  • Knowledge of combustion calculations and their requirements
  • Basic concepts of phase changes in water (liquid, steam, vapor)
NEXT STEPS
  • Research the use of steam tables for thermodynamic calculations
  • Study the enthalpy of formation for water in both gas and liquid states
  • Explore low pressure combustion calculations and their implications
  • Learn about phase changes and their effects on enthalpy values
USEFUL FOR

Chemists, chemical engineers, and students studying thermodynamics or combustion processes will benefit from this discussion, particularly those focused on enthalpy calculations involving water.

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if i have the equation for enthalpy of water


overall enthalpy = enthalpy of formation + enthalpy of water 1800k - enthalpy of water at 298k


what is the value of enthalpy of formation is it enthalpy of formation of water as gas or liquid?

enthaply at 1800k would that be enthalpy of water as steam or vapour

enthalpy at 298k would that be steam or vapour?
 
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Hi there:

If you are doing steam calculations, just go with the steam tables.

If you are doing combustion calculations, then it is another story.

In general, it would be enthalpy of formation for water. Now you have to be careful. This is tricky. For low pressure combustion calculations, you deal with steam properties that are contained in steam tables when the pressure is 1 [atm]. This should do it for you.

Good questions, but one needs to be very carerful ...

Thanks,

Gordan
 

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