Understanding Enthalpy of Formation for Water: A Comprehensive Guide

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The discussion focuses on calculating the enthalpy of formation for water, specifically at different temperatures. It clarifies that the enthalpy of formation should be considered for water in its gaseous state when dealing with steam calculations. For combustion calculations, the enthalpy values depend on the pressure conditions, particularly at 1 atm. The importance of using steam tables for accurate calculations is emphasized. Overall, careful attention to the state of water and the conditions of the calculations is crucial.
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if i have the equation for enthalpy of water


overall enthalpy = enthalpy of formation + enthalpy of water 1800k - enthalpy of water at 298k


what is the value of enthalpy of formation is it enthalpy of formation of water as gas or liquid?

enthaply at 1800k would that be enthalpy of water as steam or vapour

enthalpy at 298k would that be steam or vapour?
 
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Hi there:

If you are doing steam calculations, just go with the steam tables.

If you are doing combustion calculations, then it is another story.

In general, it would be enthalpy of formation for water. Now you have to be careful. This is tricky. For low pressure combustion calculations, you deal with steam properties that are contained in steam tables when the pressure is 1 [atm]. This should do it for you.

Good questions, but one needs to be very carerful ...

Thanks,

Gordan
 
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