What is the Variational Principle for Estimating Energy of First Excited State?

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The discussion centers on using the variational principle to estimate the ground state and first excited state energies of a particle in a potential described by V(x) = Kx^4. The wave function provided is ψ(x) = e^(-ax^2), and the true ground state wave function is symmetric, implying that the first excited state must be represented by an odd function. Participants clarify that when the inner product <ψ0|ψ(β)> = 0, the variational principle allows for estimating the first excited state energy using a trial wave function that is orthogonal to the ground state. The key takeaway is to select an odd wave function as the trial function to accurately apply the variational method for this estimation. This approach effectively utilizes the properties of wave functions and their symmetry to derive energy estimates.
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Homework Statement



A particle of mass m is in a potential of V(x) = Kx4 and the wave function is given as ψ(x)= e^-(ax2) use the variational principle to estimate the ground state energy.

Part B:
The true ground state energy wave function for this potential is a symmetric function of x i.e. ψ0(x)=ψ0(-x). Use the result that <ψ0lψ(β)> = 0 along with an approximately chosen wave function, to estimate the energy of the first excited state.



Homework Equations





The Attempt at a Solution



Ok so I know how to compute variational method approximations and I have proven the identity <ψ0lψ(β)> = 0 earlier on my assignment and understand the identity as well. What I don't understand is the part that says "Use the result that <ψ0lψ(β)> = 0 along with an approximately chosen wave function, to estimate the energy of the first excited state."

Again I know that when <ψ0lψ(β)> = 0 the variational principle becomes E1≤ <ψlHlψ>/<ψlψ> but does the problem want me to chose a different wavefunction? And if so how to I go about choosing this new wave-function?
 
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The point is to pick a wavefunction which is orthogonal to your first
and use that as a trial to read the first excited energy [again variationally].
The clue is telling you to look at the parity, an even wf. is orthogonal to an odd wf,
so your trial function should be chosen odd.
 
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