What Are the Partial Pressures and Total Pressure in a Reaction Mixture?

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SUMMARY

The discussion focuses on calculating the partial pressures and total pressure of a reaction mixture involving hydrogen (H2) and nitrogen (N2) gases reacting to form ammonia (NH33 and a temperature of 273.15 K, with 2.0 moles of H2 and 1.0 mole of N2. The total pressure is derived using the ideal gas law (PV = nRT) after determining the mole fractions of the gases involved.

PREREQUISITES
  • Understanding of the ideal gas law (PV = nRT)
  • Knowledge of mole fractions in gas mixtures
  • Basic concepts of chemical reactions and stoichiometry
  • Familiarity with units of pressure and volume
NEXT STEPS
  • Learn how to calculate partial pressures using Dalton's Law of Partial Pressures
  • Study the ideal gas law applications in various chemical reactions
  • Explore stoichiometry in gas reactions, particularly for ammonia synthesis
  • Investigate the effects of temperature and volume changes on gas mixtures
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Chemistry students, chemical engineers, and professionals involved in gas reaction processes will benefit from this discussion, particularly those focused on reaction kinetics and thermodynamics.

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[SOLVED] PCHEM/Partial Pressures Question

Problem Statement:
A vessel of volume 22.4dm^{}3 contains 2.0 mol H_{}2 and 1.0 mol of N_{}2 at 273.15K initially. All the H_{}2reacted with sufficient N_{}2 to form NH_{}3. Calculate the partial pressures and the total pressure of the final mixture.

Variables and Magnitudes:
V = 22.4dm^{}3
T = 273.15K
n_{}H_{}2= 2.0 mol
n_{}N_{}2= 1.0 mol

First Attempt:
2H_{}2+N_{}2\rightarrowNH_{}3
It takes 1.5 mol of H_{}2 to make 1 mol of NH_{}3 so I was thinking that I should say that:

p_{}H_{}2 = p_{}total*X_{}H_{}2 = ?

We would need to calculate the total pressure first for this.

I need a place to start this problem. I just can't put my finger on it.
 
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After working on the problem some more; I found that there is a simple way to do the problem. Simply find the mole fractions with the number of moles given and calculate the total pressure with PV = nRT for 3 moles, and 22.4dm^3.

Not much more to it than that. The solution in the book matches up.
 

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