Labguy said:
SpaceTiger is totally correct in the quoted post above. Plus, and I am no chemist, but wouldn't it be that: is not correct since N has only 5 electrons in the second energy level ("shell") and O has 6 electrons at that level with both elements having two electrons in the first level that would be unavailable unless ionized?..
http://www.chemicalelements.com/elements/n.html
http://www.chemicalelements.com/elements/o.html
Either way, geesh, we are only talking about an
orange moon here..
Thanks for catching my error. I must have been tired or something - my comments on relative effects of N and O probably have the correct principle, but clearly the wrong numbers. I simply forgot that the first two electrons, one spin projection up and one down, to keep Pauli happy, go in the n=1 level.
The n = 2 level has both s & p states (two again go in the s states and of the 6 possible p states (l = -1,0,1 for the 3 angular momentum variable projections, which each can hold two spin projections - i.e. 3 doubled for spin = 6 total in p states) only 3 for N and 4 for O are populated.
(I hope I still have the notation correct. I have not been to your sites, yet, but even though my Ph.D. was in another area, I was at JHU while Dr. Dieke was head of the department and most physics Ph.Ds. were related to spectroscopy then. - I could not avoid the area entirely so once spoke there language fluently.)
I now say "probably correct principle" because, even the the two "s state" electrons of the n = 2 shell have stronger (not by a lot) binding (they have less mutual screening of the nuclear charge by others because they "pass thru the nucleus," to speak classically.) I doubt if this small difference of energy levels in the n = 2 state makes any difference for visible photons, but refraction of radio waves in the ionosphere, may notice it. (I don't know - just wanted to be more careful this time, and show that it was not lack of knowledge, just tiredness that lead to my error.)
I am not an expert, but think I still have a small disagreement with you and SpaceTiger. One does not need a regular crystal structure to "keep the beam" propagating only in the forward direction. What is required, I am almost sure, is a lot of atoms inside a volume of roughly of wavelength dimensions. - so many atoms that the statistical variation is nil compared to the total.
For example glass free of bubbles etc. will coherently add the induced reradiation only in the forward direction but the very definition of glass contains the noncrystalline nature of it. You can also see this from a Hyggen (Spelling his name wrong?) approach to adding up the wavelets.
Dense clean air is another example of "forward only" propagation. - We see sharp edges to distant objects not fuzzy blurs. A distant light may be more orange, and blue is scattered out. Looking down into deep clean water also illustrates, blue and green multiple scatter, so I can not claim that there is no scattering, but if temperature variation is controlled, the forward "scatter" out of the beam is very small, despite it not being at all crystalline in either case. I think the spread of the beam in forward direction (other than diffraction -even a laser beam going to the moon grows by this.) is mainly the small effects that still do come from the small statistical variations in density, not the lack of crystallinity.
Thus, I think you and SpaceTiger are placing too much emphases on the need for a crystalline regularity (instead of random) location of the atom's whose
outer shell electrons respond to the electric field of the incident photon by reradiating their own (classical view, but we are dealing with large number of events so OK to speak this way rather than add up zillions of photon waves and get the same result.)
Considering what I have noted about dense air and glass - Do you still think the induced (re)radiation wave fronts only constructively sum in the forward direction, if the scattering (reradiating) atoms are in a crystalline array?