What Does Bond Energy Really Mean?

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SUMMARY

Bond energy is defined as the energy required to break one mole of a bond in the gas phase, specifically referring to the Cl-Cl bond in chlorine gas (Cl2). The bond energy for Cl2 is 243 kJ, which indicates that this amount of energy is necessary to break 6.02 x 10^23 Cl-Cl bonds, corresponding to one mole of Cl2 molecules. Therefore, the confusion arises from the distinction between the total number of chlorine atoms and the number of Cl-Cl bonds present in one mole of Cl2.

PREREQUISITES
  • Understanding of basic chemical bonding concepts
  • Familiarity with the mole concept in chemistry
  • Knowledge of gas phase reactions
  • Basic thermodynamics related to energy changes in chemical reactions
NEXT STEPS
  • Study the concept of bond dissociation energy in detail
  • Learn about the differences between bond energy and bond enthalpy
  • Explore the implications of bond energy on reaction mechanisms
  • Investigate the bond energies of other diatomic molecules for comparison
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Chemistry students, educators, and professionals seeking a deeper understanding of bond energy and its implications in chemical reactions.

james3444
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I'm having trouble understanding the definition of bond energy. My textbook defines it as the energy required to break 1 mole of the bond in the gas phase. I don't understand what it means to break 1 mole of a bond.
Cl2 (g) ---> 2 Cl(g) Bond energy = 243 kJ.
Since 1 mole of Cl2 is 1.2*1024 molecules, does this mean bond energy is the total energy required to break 1.2*1024 Cl-Cl bonds?
 
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One mole of Cl2 is 6.02x1023 molecules of Cl2. There are 1.2x1024 Cl atoms, but only 6.02x1023 Cl-Cl bonds. So the bond energy is the total energy required to break 6.02x1023 Cl-Cl bonds.
 

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