What is a Radioisotope Glove Box?

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SUMMARY

The BNFL plant at Sellafield, UK, reported a 'loss' of 30kg of plutonium during nuclear fuel reprocessing, attributed to measurement inaccuracies rather than theft. This discrepancy arises from the need to calculate plutonium amounts at various stages, leading to potential bookkeeping errors. Historical data shows similar unaccounted amounts, with 5.6kg in 2001 and 24.9kg in 1999. The security measures in place at Sellafield, including operations conducted in 'hot cells' or 'glove boxes', ensure that the plutonium remains contained despite these measurement uncertainties.

PREREQUISITES
  • Understanding of nuclear fuel reprocessing techniques
  • Familiarity with plutonium handling and safety protocols
  • Knowledge of measurement accuracy and error analysis in scientific contexts
  • Awareness of historical data related to nuclear material accountability
NEXT STEPS
  • Research the operational protocols of BNFL Sellafield regarding plutonium handling
  • Study measurement techniques and error analysis in nuclear material accounting
  • Explore the design and function of radioisotope glove boxes in nuclear facilities
  • Investigate historical cases of plutonium discrepancies and their implications
USEFUL FOR

Nuclear physicists, safety regulators, and professionals involved in nuclear fuel management and accountability will benefit from this discussion.

Kieron
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Hi
The BNFL plant at Sellafield in the UK is reported to have ‘lost’ 30kg of plutonium in the reprocessing nuclear fuel. It is reported as a paper loss due to the limits of accurate measurement within the process. Due to the lack of information in the news reports I am left a little confused. Are they saying then had x kg ± y kg at the start of the process now they have x-30 kg where 30kg is within the boundaries of the margin of error. Or is the 30Kg more then one expect to have to account for given the problems of measurement in the process

Kieron
 
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Depending on which newspaper you read, between 30 and 80kg was unaccounted for. Officially, it hasn't been lost or stolen, but apparently fuel can occasionally get misplaced during handling routines (!), and the 'paper loss' claim was also used. Apparently at various stages in the process, the amount of plutonium has to be calculated rather than measured, and this has also been reported as a cause of the error.

This 'misplaced' plutonium has been reported more than once (in 2001 5.6kg was unaccounted for, in 1999 24.9kg), and these amounts are totals for the entire year and not just overnight. Newspapers and action groups argue "how can BNFL say that it hasn't been stolen?", a question which is easily answered merely by looking at the amount of security around Sellafield.

Morbius?
 
Here is some background on Sellafield.

http://www.bellona.no/en/energy/nuclear/sellafield/wp_5-2001/21736.html

The question is how many tonnes of spent fuel has been reprocessed. Then how much of that was Pu. In 1 metric ton (1000 kg of spent fuel) there might be 10 to 30 kg Pu. If several hundred (or thousands) of metric tons of spent fuel was reprocessed, it is conceivable that an uncertainty of 30 kg's of Pu might accumulate through a combination of book-keeping errors and simple loss into the waste stream a few grams at a time.

Records keeping between 1950 and up to the end of the 1970's was largely paper, which was then transferred to computer (perhaps). The was before the digital age of PCs and large networks.
 
Last edited by a moderator:
Kieron said:
Hi
The BNFL plant at Sellafield in the UK is reported to have ‘lost’ 30kg of plutonium in the reprocessing nuclear fuel. It is reported as a paper loss due to the limits of accurate measurement within the process. Due to the lack of information in the news reports I am left a little confused. Are they saying then had x kg ± y kg at the start of the process now they have x-30 kg where 30kg is within the boundaries of the margin of error. Or is the 30Kg more then one expect to have to account for given the problems of measurement in the process

Kieron

Kieron,

Given that the BNFL plant at Sellafield has reprocessed many, many
TONS of spent nuclear fuel - 30 Kg is not a lot. One full core load for
a single reactor is about 100 tons. So each full core load has about
2 tons of plutonium.

Sellafield has reprocessed many, many full core equivalents of spent
nuclear fuel over the few decades that it has been in operation.
I would tend to think 30 Kg/yr is well within the margin of error.

In fact, I would have expected an even larger number than 30 Kg. If it's
that low - they must be doing a very good job.

Dr. Gregory Greenman
Physicist
 
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brewnog said:
Depending on which newspaper you read, between 30 and 80kg was unaccounted for. Officially, it hasn't been lost or stolen, but apparently fuel can occasionally get misplaced during handling routines (!), and the 'paper loss' claim was also used. Apparently at various stages in the process, the amount of plutonium has to be calculated rather than measured, and this has also been reported as a cause of the error.

This 'misplaced' plutonium has been reported more than once (in 2001 5.6kg was unaccounted for, in 1999 24.9kg), and these amounts are totals for the entire year and not just overnight. Newspapers and action groups argue "how can BNFL say that it hasn't been stolen?", a question which is easily answered merely by looking at the amount of security around Sellafield.

Morbius?

brewnog,

You've summarized it pretty well.

One has to remember that when you "assay" the material - to find out
how much you have - you weigh it. Put a sample of plutonium on your
scale and the scale tells you it weighs 2.5 Kilograms. However, that
sample may really weigh 2.5000001 Kilograms. The scale isn't showing
you that 0.1 milligram overage - it's not 100% accurate. So you just
"lost" 0.1 milligram of plutonium.

It's not really lost - your scale just didn't report it properly. There are
only so many digits on the display. Or when you wrote it in the books,
you rounded the number off to 2.500 Kg.

That's how you can "lose" 0.1 milligrams. Now do that over and over
again, day in and day out for a year - multiplied by many people doing
the measuring - and you can well lose 30 Kg "on paper".

However, the plant has a lots of security because it handles plutonium.
All the operations with plutonium are done in "hot cells", or "caves" or
"glove boxes". Even though your balance makes a small error - that
plutonium hasn't gotten out of the "hot cell" or "glove box". It's still
there - you just lost track of it on paper.

So it's doubtful that anyone has smuggled that material out of the
plant - the 30 Kg is just the accumulation of all the uncertainties.

Dr. Gregory Greenman
Physicist
 
Judging by the strict controls they have there (and after Sept 11th I noticed they got a *lot* stricter) there's no way that someone could have stolen anything at all from Sellafield, without them noticing.
 
Morbius said:
However, the plant has a lots of security because it handles plutonium. All the operations with plutonium are done in "hot cells", or "caves" or "glove boxes".
Here is a nice pic of a radioisotope glove box, by the way:
http://photos.groups.yahoo.com/group/know_nukes/vwp?.dir=/Peter+Essick+USA+National+Geographic+Ma&.dnm=glovebox.jpg&.src=gr&.view=t&.hires=t
 
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