What is the Best Method for Titration of a Weak Acid with a Strong Base?

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SUMMARY

The discussion focuses on titrating a weak acid with a standardized sodium hydroxide solution (0.1M). It is established that the equivalence point for this titration occurs at a pH greater than 7 due to the formation of a salt from the reaction. The final pH can be used to determine the pKa of the weak acid. The conversation also touches on the practicality of using calcium carbonate as a weak base for neutralizing strong acids, emphasizing the importance of understanding the pH changes throughout the titration process.

PREREQUISITES
  • Understanding of titration principles
  • Knowledge of pH and pKa concepts
  • Familiarity with strong and weak acids and bases
  • Basic skills in using pH indicators or pH meters
NEXT STEPS
  • Research the concept of equivalence points in acid-base titrations
  • Learn about the Henderson-Hasselbalch equation for buffer solutions
  • Study the properties of calcium carbonate as a weak base
  • Explore methods for determining pKa values experimentally
USEFUL FOR

Chemistry students, laboratory technicians, and anyone involved in acid-base titration experiments seeking to understand the nuances of weak acid and strong base interactions.

[aq]
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Hiya,

Im trying to determine the initial molarity of an unknown acid, sooo I am trying to titrate it with standardized sodium hydroxide solution (0.1M). But I am having a load of problems figuring out what the heck I am supposed to do since i am told the acid is a weak acid.

If I am titrating a weak acid using a strong base the equivalence point is at a pH level greater than 7 correct?

But I am not supplied with information regarding anything about the acid except that it is weak, and nothing about the pH at the equivalence point!

How would i go about doing this titration ? Does buffers have anything to do with this (since according to my textbook, the acid-base buffer should form around the halfway point to the equivalence point).
 
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Buffers do not have anything to do with it since strong acid/bases have no relation to buffers.

here are some hints:

Titrate to completion, at the equivalence point, that is when the acid and base have reacted in stoichiometric equivalence, the final pH will be determined by the salt formed in the reaction.

from this pH you should be able to determine the pKa of the weak acid.
 
Why is it better to use a weak base(such as calcium carbonate) to neutralise strong acid (such as hcl) rather than strong base?

Thank you so much
 
Please don't hijack threads.

And remember we want you to try first. You do have some ideas, don't you?
 
Last edited:
no i don't have a correct answer but i think it is because weaker acid is less likely to make the solution alkali therefore acidic salt is produced
 
If you start with a neutral solution, and you add calcium carbonate, what will be the final pH?
 
Borek said:
If you start with a neutral solution, and you add calcium carbonate, what will be the final pH?

The use of Calcium Carbonate might be a choice to employ the insolubility of calcium carbonate after all of the acid is neutralized, but is this practical/useful?

This "hijack" was also on another board, and I gave a response there.

BETTER: Start a new topic and not continue this "Calcium Carbonate - Strong Acid" topic here.
 

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