What is the Color of Green Copper?

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SUMMARY

The color of the Statue of Liberty, which is green, results from the oxidation of copper. Pure copper appears orange, while copper hydroxide is blue and copper oxide is black. The green color is primarily due to the formation of copper carbonate, a product of copper reacting with carbonic acid in rainwater. This process leads to the creation of cupric and cuprous carbonate, which are responsible for the green patina observed on oxidized copper surfaces.

PREREQUISITES
  • Understanding of basic chemistry concepts, particularly oxidation states.
  • Familiarity with copper compounds, specifically copper carbonate.
  • Knowledge of environmental chemistry, including the effects of carbonic acid.
  • Awareness of the properties of metals and their reactions with environmental elements.
NEXT STEPS
  • Research the chemical properties and reactions of copper carbonate.
  • Explore the process of metal oxidation and its environmental factors.
  • Learn about the historical significance and preservation techniques of copper structures.
  • Investigate the role of carbonic acid in weathering and its effects on various metals.
USEFUL FOR

This discussion is beneficial for chemistry students, environmental scientists, and professionals involved in the preservation of historical metal structures, particularly those interested in the chemical processes that lead to oxidation and patina formation.

ShawnD
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Pure copper metal is orange (or pink after being anodized), copper hydroxide is blue, copper oxide is black. So then why is the statue of liberty green?
 
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Supposedly its oxidation... and I've seen copper turn green though too..
 
I've seen lots of old pennies turn green. Must be the same thing.
 
I'm no chemist, but I believe there are several different oxidation states of copper, one of which is green.

- Warren
 
ShawnD said:
Pure copper metal is orange (or pink after being anodized), copper hydroxide is blue, copper oxide is black. So then why is the statue of liberty green?

My guess was copper sulfate, but I looked it up and its probably more likely copper carbonate. As you may have learned in your intro chem classes(especially if your teacher was an environmental guy like mine) water reacts with carbon dioxide to form carbonic acid, which gives all rain its slight acidity. This carbonic acid will then react with the copper to form cupirc and cuprous carbonate.
 
sulfates and acetates will turn it green.
 

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