What is the Density of States for Electrons in Metal?

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Discussion Overview

The discussion revolves around the calculation of the density of states for electrons in metals, particularly focusing on the derivation and factors influencing the density of states formula. It includes theoretical considerations and mathematical reasoning related to quantum mechanics and solid-state physics.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Exploratory

Main Points Raised

  • One participant presents a derivation of the density of states for electrons in a metal, starting from the quantized energy levels of a quantum ideal gas.
  • The participant introduces variables for the quantum numbers and discusses the relationship between energy and the density of states, leading to a proposed formula for N(E).
  • Another participant points out that each electron has two possible spin states, which is suggested as the reason for a factor of two in the density of states calculation.
  • A later reply acknowledges the spin states and expresses gratitude for the reminder.
  • Another participant seeks assistance in calculating the density of states from phonon dispersion relations, indicating a different focus within the same broader topic.

Areas of Agreement / Disagreement

There is no explicit consensus on the source of the factor of two in the density of states formula, though the mention of spin states is acknowledged. Additionally, the discussion about phonon dispersion relations introduces a separate line of inquiry that remains unresolved.

Contextual Notes

The discussion does not clarify the assumptions made in the derivation of the density of states, nor does it resolve the mathematical steps involved in transitioning from the electron model to the phonon model.

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Consider electrons in metal as a quantum ideal gas, the quantized energy would be

[tex] E(n_x, n_y, n_z) = \frac{h^2}{8m}\left(\frac{n_x^2}{L_x^2} + \frac{n_y^2}{L_y^2} + \frac{n_z^2}{L_z^2}\right)[/tex]

Now, letting

[tex] \alpha = \frac{n_x}{L_x}, \qquad \beta = \frac{n_y}{L_y}, \qquad \gamma = \frac{n_z}{L_z}[/tex]

and

[tex] \rho^2 = \alpha^2 + \beta^2 + \gamma^2[/tex]

and setting up an coordinate with [tex]\alpha, \beta, \gamma[/tex]. One could see that the volume b/w E-E+dE is proportional to the volume b/w [tex]\rho - \rho + d\rho[/tex]

Note that the volume within [tex]\rho - \rho + d\rho[/tex] is just one-eighth of the volume of the spherical shell with thickness [tex]d\rho[/tex], namely,

[tex]V_\rho = \frac{4\pi \rho^2 d\rho}{8}[/tex]

Hence, the density of states within [tex]\rho - \rho + d\rho[/tex] becomes

[tex]N(\rho)d\rho = \frac{V_\rho}{\textnormal{volume per state}} = \frac{4\pi\rho^2d\rho /8}{1/V} = \frac{\pi V \rho^2 d\rho}{2}[/tex]

Well, we know that

[tex]E = \frac{h^2}{8m}\rho^2[/tex]

in addition

[tex] N(\rho)d\rho = N(E)dE [/tex]

which gives

[tex] N(E) = \frac{1}{2}\frac{\pi V}{2}\left(\frac{8m}{h^2}\right)^{3/2}\sqrt{E}[/tex]

But the correct answer for density of state in energy should be (two times of the above reuslt), i.e.

[tex] N(E) = \frac{\pi V}{2}\left(\frac{8m}{h^2}\right)^{3/2}\sqrt{E}[/tex]

Where is the '2' come from?

Someone suggests

[tex]N(\rho)d\rho = 2\times\frac{\pi V \rho^2 d\rho}{2}[/tex]

This will give the correct answer, but where is "2" come form?
 
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Each electron has two possible spin states.
 
Avodyne said:
Each electron has two possible spin states.

Oh, how can I forget that! Thanks a lot :)
 
Can someone help me calculating the density of states from phonon dispersion relations.
I have computed the phonon dispersion relations from considering the vibrations of crystals. Now as a next step, i want to compute the density of states. not sure how.
many thanks in advance for your help
 

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