What is the entropy of three cue balls in a bucket?

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Homework Help Overview

The discussion revolves around calculating the entropy of three identical cue balls in a cylindrical bucket, focusing on two specific states: one where the balls are at rest and touching each other and the bucket, and another where their coordinates and momenta are specified. The original poster expresses uncertainty about the definition of macrostates in this context and how to quantitatively express entropy.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster questions the definition of macrostates and how to identify them in this scenario. They also explore the relationship between microstates and macrostates, particularly in terms of the arrangement of the balls and their energy. Other participants suggest that more details are needed to clarify the states and the independence of the momenta of the balls.

Discussion Status

Participants are providing insights into the relationship between microstates and macrostates, with some suggesting that the original poster needs to specify additional details. There is an emphasis on understanding the constraints of the system and how they affect the calculation of entropy.

Contextual Notes

There is a noted concern regarding the sufficiency of information provided to determine the entropy, particularly in defining macrostates in terms of traditional thermodynamic variables. The original poster's understanding of entropy as a measure of microstates is acknowledged, but the application to this specific problem remains unclear.

jjustinn
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I posted this question a couple days back, but it got removed because it looked like a homework question (which, I suppose, is flattering, since I came up with it on the way home from work, and I'm not even a student, let alone a teacher)...so I'm going to try to rephrase it -- but because this is the most concise formulation I could think of, here's the original:

Given a cylindrical bucket of radius R, and three identical cue balls of radius r inside of it, what is the entropy of...

(1) ...the state where all three balls are at rest, touching each other, and touching the side of the bucket?

(2) ...the state where the coordinates of the balls are (r1, θ1), (r2, θ2), (r3, θ3) and the momenta are (p1, ω1), (p2, ω2), (p3, ω3) for balls #1, #2, #3, respectively?

Assume the bucket is fixed (immobile) and the balls are constrained to roll along the plane z=0 (they cannot bounce)

I'm not even sure there's enough information there to get the entropy; because, if I understand correctly, the entropy is a measure of the number of "microstates" (in this case, the coordinates/momenta of each ball) that give rise to a given "macrostate"...and I'm not sure what a macrostate would be here: I can't think of any "macro" variables analogous to heat, etc.
The closest I can think of would be that you would get the same "macrostate" by swapping any of the identical balls, or rotating the bucket...

I picked the state in (1) because it seemed like it would be the state with the highest entropy, because intuitively, if you dropped three cueballs in a bucket and rattled it around, eventually the balls would settle down next to each other on the side...but I'm trying to figure out away to express this quantitatively.

So, any guidance, corrections, thoughts, musings, etc would be appreciated.

Thanks.
 
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S = k log(W), where W is the number of microstates accessible to the system.

For each microstate available the total energy of the system is unchanged. Different microstates are rearrangements of the energy of the system. See:
http://entropysite.oxy.edu/microstate/
 
UltrafastPED said:
S = k log(W), where W is the number of microstates accessible to the system.

For each microstate available the total energy of the system is unchanged. Different microstates are rearrangements of the energy of the system. See:
http://entropysite.oxy.edu/microstate/
In the OP, there are two macrostates. In each, all the microstates have the same energy, so you can compare the entropies of the macrostates.
jjustinn, I think you need to specify more details. The way you describe (1), the three balls only just fit in the bottom of the bucket. That being so, the momenta of the same three balls moving in the bottom of the bucket are not independent.
 
I don't plan to solve his question - instead I provide tools for him to do his own analysis.

Also macrostates, as I understand them, are measured by temperature, pressure, etc. When you have to count things, they are microstates.
 

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