What is the equation for U in the Equipartition Theorem?

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Hypervalent_Iodine
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Homework Statement
Use the equipartition theorem to estimate the heat capacity of
(i) carbon dioxide, (ii) methane.
Relevant Equations
C=dU/dT
.
 
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Per PhysicsForums rules, we require that you present an attempt at a solution.

In your relevant equations, an equation for ##U## would also be useful.