What is the Molecular Formula of Dieldrin?

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Discussion Overview

The discussion revolves around determining the molecular formula of the insecticide dieldrin based on experimental data involving combustion products. Participants explore the calculation of moles from the combustion of a sample and the implications of the given stoichiometric relationships.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents a sample of dieldrin and the products of its combustion, seeking assistance in deriving the molecular formula.
  • Another participant suggests converting the masses of CO2 and H2O produced into moles to help determine the moles of carbon, hydrogen, and oxygen.
  • A participant shares their calculation attempt, arriving at a molecular formula of C6H4O14Cl3, but notes that the calculated molar mass does not match the expected value of 381 g/mol.
  • There is a discrepancy noted by the same participant regarding the calculation of moles of oxygen derived from CO2 and H2O, leading to uncertainty about which value is correct.
  • One participant cites an online source claiming the molecular formula of dieldrin is C12H8Cl8O, which is challenged for not adhering to the provided stoichiometric relationship of chlorine atoms being half that of carbon atoms.
  • A later reply corrects the previous online claim, stating the molecular formula is C12H8Cl6O, but this still raises questions about the initial conditions given in the problem.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the correct molecular formula for dieldrin, with multiple competing views and calculations presented. There is also uncertainty regarding the correct method for calculating the moles of oxygen.

Contextual Notes

Participants express limitations in their calculations, particularly regarding the differing amounts of oxygen derived from CO2 and H2O. The discussion also highlights the dependence on the initial conditions and assumptions provided in the problem.

PhysicsinCalifornia
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The insecticide deildrin contains carbon, hydrogen, oxygen, and chlorin. 1.5100g sample of this compound is burned to produce 2.0938g CO2 (g) and 0.2855g H2O(g). They're half as many chlorine atoms as carbon atoms in the compound. The molar mass of the dieldrin is 381g/mole. What is the molecular formula?

I don't know where to start on this. Can anyone give me a jumpstart? Thanks
 
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How about converting the masses in moles...:smile:
 
I just attempted this and got an answer of C6H4O14Cl3, but the molecular mass of that is 406 and not 381 :(.

I'll lay out what I did anyways and maybe you can spot my mistake and be able to figure it out for yourself :).

-convert carbon dioxide and water to moles, and then you'll be able to figure out moles of C, H, and O
-divide by the smallest amount of moles to get decimal ratios between the elements' moles
-then add in the moles of Cl, which is half the moles of C (given in the problem)
-finally multiply formula to get all whole numbers
 
ksinclair13 said:
I just attempted this and got an answer of C6H4O14Cl3, but the molecular mass of that is 406 and not 381 :(.

I'll lay out what I did anyways and maybe you can spot my mistake and be able to figure it out for yourself :).

-convert carbon dioxide and water to moles, and then you'll be able to figure out moles of C, H, and O
-divide by the smallest amount of moles to get decimal ratios between the elements' moles
-then add in the moles of Cl, which is half the moles of C (given in the problem)
-finally multiply formula to get all whole numbers

That's actually how I started on this problem.

The only thing is that if I calculate the mole using CO2 and H2O, the mole will be different for O. Using CO2, I got 0.095151 moles of O, but with H2O, I got 0.015847 mol of O.
Which one is right?
 
Hey, I looked up the formula for dieldrin online. The molecular formula is
C_{12}H_8Cl_8O
www.chemfinder.com
 
But that doesn't follow the half as much Cl as C, and that has a molecular mass of about 452 g/mol.
 
PhysicsinCalifornia said:
Hey, I looked up the formula for dieldrin online. The molecular formula is
C_{12}H_8Cl_8O
www.chemfinder.com

Sorry, the molecular formula is
C_{12}H_8Cl_6O

Thanks for the help
 

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