What is the normalisation condition for a quantum mechanics problem?

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Homework Help Overview

The discussion revolves around the normalization condition in quantum mechanics, specifically related to the wavefunction and its implications for observables such as energy. Participants are examining the mathematical formulation of normalization and its consequences for the properties of the wavefunction.

Discussion Character

  • Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to derive the normalization condition and explore the implications for energy observables. Some participants question the phrasing regarding energy as an eigenvalue and discuss the nature of sharp observables in relation to the wavefunction's form.

Discussion Status

Participants are actively engaging with the mathematical aspects of the problem and clarifying terminology. There is a recognition of the correctness of the mathematics presented, but also a push for clearer language regarding the concepts of eigenvalues and observables. Multiple interpretations of the wavefunction's properties are being explored.

Contextual Notes

There is a mention of standard practices in notation and formulation within quantum mechanics, indicating a potential gap in the original poster's understanding. The discussion also touches on the limitations of the wavefunction's current form in relation to the Hamiltonian operator.

QuantumJG
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Homework Statement



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Homework Equations



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The Attempt at a Solution



i.)

Normalisation implies that:

\int_{-\infty}^{\infty} \Psi (x,t)* \Psi (x,t) dx = 1

\int_{-\infty}^{\infty} |a_{0}| ^{2} | \psi _{0} (x) | ^ {2} + |a_{1}| ^{2} | \psi _{1} (x) | ^ {2} dx = 1

After a bit of work I got to this line

|a_{0}| ^{2} \int_{-\infty}^{\infty} | \psi _{0} (x) | ^ {2} dx + |a_{1}| ^{2} \int_{-\infty}^{\infty} | \psi _{1} (x) | ^ {2} dx = 1

|a_{0}| ^{2} + |a_{1}| ^{2} = 1

i.e. I found this to be the normalisation condition.

ii.)

First to see if the energy is an eigenvalue

[E] \Psi (x,t) = i \hbar \dfrac{d}{dt} \left( a _{0} \psi (x) e^{ - \dfrac{i E_{0} t }{ \hbar } } + a _{1} \psi (x) e^{ - \dfrac{i E_{1} t }{ \hbar } } \right)

[E] \Psi (x,t) = E_{0} a _{0} \psi (x) e^{ - \dfrac{i E_{0} t }{ \hbar } } + E_{1} a _{1} \psi (x) e^{ - \dfrac{i E_{1} t }{ \hbar } }

So the energy is not an eigenvalue and hence the energy is not a sharp observable.

\langle E \rangle = \int_{-\infty}^{\infty} \left( a _{0} * \psi (x) * e^{ \dfrac{i E_{0} t }{ \hbar } } + a _{1} * \psi (x) * e^{ \dfrac{i E_{1} t }{ \hbar } } \right) \left( E_{0} a _{0} \psi (x) e^{ - \dfrac{i E_{0} t }{ \hbar } } + E_{1} a _{1} \psi (x) e^{ - \dfrac{i E_{1} t }{ \hbar } } \right)

\langle E \rangle = E_{0} |a_{0}| ^{2} + E_{1} |a_{1}| ^{2}

\langle E \rangle = E_{0} |a_{0}| ^{2} + E_{1} (1 - |a_{0}| ^{2} )

\langle E \rangle = |a_{0}| ^{2} ( E_{0} - E_{1} ) + E_{1}

\langle E \rangle = |a_{0}| ^{2} ( \dfrac{1}{2} \hbar \omega - \dfrac{3}{2} \hbar \omega ) + \dfrac{3}{2} \hbar \omega

\langle E \rangle = \hbar \omega \left( \dfrac{3}{2} - |a_{0}| ^{2} \right)

I'm not 100% sure if this is right.
 

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The mathematics is correct!

You might want to rephrase your answer to the question about the energy not being a sharp observable: saying "the energy is not an eigenvalue" does not really make sense.

PS it is also more standard to write H instead of |E|.
 
Ok but isn't a sharp observable one where if you apply it's corresponding operator to the wavefunction you get a constant times the wavefunction. The constant is an eigenvalue. But in this case the wavefunction isn't an eigenfunction, thus the observable isn't sharp.

It is more standard to apply the Hamiltonian operator, but the wavefunction isn't really in a form where if you apply the hamiltonian you will get something tangible.
 
QuantumJG said:
Ok but isn't a sharp observable one where if you apply it's corresponding operator to the wavefunction you get a constant times the wavefunction. The constant is an eigenvalue. But in this case the wavefunction isn't an eigenfunction, thus the observable isn't sharp.

I was referring more to the way things were formulated. Saying "the energy is not an eigenvalue" does not really make sense. There is no "the energy"; the wavefunction is in a superposition. It's better to formulate it as: the wavefunction is not an eigenfunction of the Hamiltonian, and therefore energy is not a sharp observable.

It is more standard to apply the Hamiltonian operator, but the wavefunction isn't really in a form where if you apply the hamiltonian you will get something tangible.

Exactly in what way is tangible a criteria? The Hamiltonian is the operator associated with energy. But that does not imply that if you act on a wavefunction you obtain the corresponding energy.
 
If you know about the matrix notation, it might make things easier to work out. That's how I would do this problem but your solution seems correct to me.
 

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