What is the significance of using electron-volts in chemistry?

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Discussion Overview

The discussion revolves around the use of electron-volts in the context of chemistry, specifically regarding cell potentials in batteries. Participants explore whether it is appropriate to use electron-volts as a unit of electric potential and seek clarification on its applications in both physics and chemistry.

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • PWood questions the correctness of using electron-volts as a unit of electric potential, noting that it is typically a unit of energy.
  • Another participant explains that electron-volts are convenient for expressing very small amounts of energy, equating 1 eV to 1.6 x 10^-19 J.
  • PWood reiterates the inquiry about the use of electron-volts specifically as a unit of electric potential, expressing doubt about its correctness in that context.
  • A participant presents two scenarios: one where the instructor might be mistaken, and another where the instructor could be conflating energy and potential, as 1 eV represents the energy gained by an electron when accelerated through a potential difference of 1 Volt.
  • Another participant suggests that the instructor might be referring to standard electrode potentials expressed in volts.

Areas of Agreement / Disagreement

Participants express differing views on the appropriateness of using electron-volts as a unit of electric potential. There is no consensus on whether this usage is correct, and the discussion remains unresolved.

Contextual Notes

Participants acknowledge the potential for confusion between energy and electric potential, but do not resolve the underlying issues regarding definitions and applications.

pwood
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Hi all,
My instructor in my college chemistry class continually refers to cell potentials (as in battery cell potentials) in units of electron-volts. Is there any case in physics or chemistry where this is correct? My understanding is that an electron-volt is generally a unit of energy, but I didn't think it was correct to use it for electric potential, cell or not.
Thanks,
PWood
 
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Electron volts are used when the energy involved is extremely small.

1 eV = 1.6 x 10^-19 J...so when you are talking about very small amounts of energy, it is more convenient to express the energy as an eV than a joule.
 
Hi Woopydalan,

I appreciate your post, but I already stated that I knew that it was a unit of energy. What I am asking is: are there any uses of the electron-volt that interpret it as a unit of electric potential? That is how my chemistry instructor uses it, I believe incorrectly.

I am aware that it is used in some fields as a unit of mass, momentum, and distance. I am in doubt that it is ever used as a unit of electric potential.

So, that is the question: is it ever (correctly) interpreted as a unit of electric potential?
 
Two cases : Either the professor is taking off on wrong foot (happens all the time) or he actually may mean another thing.

Case 1: Just delete the term electron in your mind. You're more than happy person.

Case 2: 1 Electron volt is the energy of an electron when it is accelerated by the potential difference of 1 Volt. Since in electrochemistry, the cells (or Redox couple) we make have some electrons transfer from Anode to Cathode, accompanied by the generation of Potential, "Maybe" he may had mixed those two things as one.

Your best bet is still to ask him loud and clear. And if you are afraid, ask him in a form of a textbook question, in which the answer is in form of Volts.
 
He's probably expressing the potential as Eo Volts... which is a standard electrode (the "Eo" part) in units of volts.
 

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