What is the Source of Strange Sewer-Like Fumes Causing Reactions?

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Discussion Overview

The discussion revolves around the challenges of sealing containers and structures to prevent the infiltration of gases, particularly hydrogen sulfide (H2S) from sewage systems. Participants explore various materials and methods for achieving airtight seals, the properties of gases, and the implications for building design and safety.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • Some participants suggest that the airtight property of jar lids is not solely due to metal seals but may involve an intermediate layer that aids in creating a seal.
  • Concerns are raised about the expansion of metal when heated, potentially creating microscopic gaps that could allow air to pass through.
  • Hydrogen and helium can diffuse through certain metals and glass, with diffusion rates influenced by temperature and pressure rather than just material tension.
  • One participant mentions that hydrogen gas can migrate through many metals, while larger gas molecules like H2S diffuse more slowly due to their size.
  • There is a discussion about the effectiveness of various materials, such as nitrile and closed cell foam, in blocking gases, with skepticism expressed about their performance.
  • Participants explore the idea of using double wall containers with a "getter" to absorb hydrogen for better sealing against gas migration.
  • Ventilation strategies are proposed as potential solutions to manage gas infiltration in dwellings, including drainage and air circulation methods.
  • There is a suggestion that sources of heat, such as pilot lights or fires, could help dissipate gases, though this is met with some confusion and requests for clarification.
  • One participant raises the possibility of using ozone generators to convert H2S into sulfur dioxide (SO2), questioning the safety and implications of such an approach.

Areas of Agreement / Disagreement

Participants express various viewpoints on the effectiveness of different sealing materials and methods, indicating a lack of consensus on the best approach to prevent gas infiltration. The discussion remains unresolved with multiple competing views on the efficacy of proposed solutions.

Contextual Notes

Participants note limitations regarding the performance of sealing materials, the conditions under which gases diffuse, and the potential risks associated with different gases and their management in building environments.

Who May Find This Useful

This discussion may be of interest to those involved in building design, materials science, environmental engineering, and anyone concerned with indoor air quality and gas management in residential or commercial structures.

  • #31
And then return it?
 
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  • #32
No, this one would be a keeper. I tried to attack the video but this site only attaches photos.
 
  • #33
Do you know if the multi-gas detectors that firemen use, can detect carbon disulfide?
 
  • #34
Why do you ask?
 
  • #35
E4475FC8-BDD4-4A6A-A7B9-B4BBAED89CB1.jpeg
 
  • #36
Um, could you please use your words?
 
  • #37
Per our previous conversation, I am investigating these strange sewer like fumes to which I react. Is there a possibility that I am reacting to a combination of H2S and CH4?
 
  • #38
moriah said:
I am investigating these strange sewer like fumes to which I react. Is there a possibility that I am reacting to a combination of H2S and CH4?
I would discount carbon disulfide, CS2, as the smell you report. Carbon disulfide does not smell bad. There are many other more common sulfur based contaminants that stench, and so will mask the sweeter smell of CS2.

CS2 will not be produced by reactions in sewer gas. The synthesis of CS2 require an industrial process at much higher temperatures.

CS2 is a neurotoxin. In high concentrations it is known to cause psychosis in industrial workers. I am confident that CS2 is not at sufficient levels to cause you to imagine the problem.

The odor you are sensing is probably a thiol or thiol derivative. We are very sensitive to the smell of those compounds.
https://en.wikipedia.org/wiki/Thiol#Odor
 

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