What is the true definition of an ionic liquid?

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    Ionic Liquid
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Discussion Overview

The discussion revolves around the definition of "ionic liquid," exploring its characteristics, distinctions from other solutions, and historical context. Participants examine the nuances of terminology and the implications of various definitions in scientific literature.

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant questions the definition of ionic liquid, contrasting it with a simple NaCl solution in water and seeking clarity on the differences.
  • Another participant asserts that "NaCl ionic liquid" is not a recognized term, suggesting that ionic liquids are typically salts that remain liquid at room temperature, while molten salts may also be considered ionic liquids in some contexts.
  • There is a historical reference to ethylammonium nitrate as the first true ionic liquid, with questions raised about its miscibility with water and the criteria for classification as an ionic liquid.
  • Some participants express uncertainty about the exact definition of ionic liquid, indicating that the term may be used loosely in literature, leading to confusion.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the definition of ionic liquid, with multiple competing views and uncertainties remaining regarding the terminology and its application.

Contextual Notes

There are limitations in the discussion regarding the definitions used, the conditions under which substances qualify as ionic liquids, and the reliance on historical context without clear consensus on terminology.

Nahahahah
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Hi. I have a question about the term, "Ionic liquid"

When I researched the papers, I found the word "Ionic liquid" in many papers.

First, I thought the ionic liquid just means the solution that solvent is ionized.

But as I read other papers, I found that people don't mean ionized solution as ionic liquid.

For example... What is a difference between (1) NaCl ionic liquid and... just a (2) solution that I pour NaCl powder in DI water and just it with stick ?I hope I find the answer here...

Thanks!
 
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There is no such thing as "NaCl ionic liquid*", but I know what you are trying to say.

A terminologically incorrect* but intuitive analogy would be molten salt. Ionic liquid is like a molten salt except the melting temperature is below RT.
*We usually refer to ionic liquid as salts that are liquid in RT. However, in a broader sense, molten salt is also considered an ionic liquid in some literature on ionic liquids. I am not sure if this is for sake of discussion in trying to let the readers intuitively understand, or if this term is technically correct under the definition.
 
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HAYAO said:
There is no such thing as "NaCl ionic liquid", but I know what you are trying to say.

A terminologically incorrect but intuitive analogy would be molten salt. Ionic liquid is like a molten salt except the melting temperature is below RT.
Thank you so much!
 
First discovered true ionic liquid, by Walden in 1914, was ethylammonium nitrate.
Is ethylammonium nitrate miscible with water?
At which point does it cease to qualify as "ionic liquid"?
 
snorkack said:
First discovered true ionic liquid, by Walden in 1914, was ethylammonium nitrate.
Is ethylammonium nitrate miscible with water?
At which point does it cease to qualify as "ionic liquid"?
Quick research says that it is miscible with water at any composition.

I don't know the exact definition of "ionic liquid". In a broad sense, even molten salt is ionic liquid. The nomenclature "ionic liquid" seems to be something that many people take what other people says for granted, instead of trying to be very specific about it.
 
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