What is the Variational Principle for Estimating Energy of First Excited State?

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SUMMARY

The discussion focuses on using the variational principle to estimate the energy of the first excited state for a particle in a potential defined by V(x) = Kx4. The wave function provided is ψ(x) = e-ax2, and the key takeaway is that the trial wave function must be orthogonal to the ground state wave function, which is symmetric. The identity <ψ0|ψ(β)> = 0 indicates that the variational principle simplifies to E1 ≤ <ψ|H|ψ>/<ψ|ψ>, necessitating the selection of an odd trial wave function to estimate the first excited state energy.

PREREQUISITES
  • Understanding of the variational principle in quantum mechanics
  • Familiarity with wave functions and their properties
  • Knowledge of potential energy functions, specifically V(x) = Kx4
  • Ability to compute expectation values in quantum mechanics
NEXT STEPS
  • Study the variational method for estimating quantum state energies
  • Learn about orthogonal wave functions and their significance in quantum mechanics
  • Explore the properties of even and odd functions in relation to quantum states
  • Investigate the implications of the variational principle on excited state energies
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focusing on variational methods and energy estimations for quantum systems.

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Homework Statement



A particle of mass m is in a potential of V(x) = Kx4 and the wave function is given as ψ(x)= e^-(ax2) use the variational principle to estimate the ground state energy.

Part B:
The true ground state energy wave function for this potential is a symmetric function of x i.e. ψ0(x)=ψ0(-x). Use the result that <ψ0lψ(β)> = 0 along with an approximately chosen wave function, to estimate the energy of the first excited state.



Homework Equations





The Attempt at a Solution



Ok so I know how to compute variational method approximations and I have proven the identity <ψ0lψ(β)> = 0 earlier on my assignment and understand the identity as well. What I don't understand is the part that says "Use the result that <ψ0lψ(β)> = 0 along with an approximately chosen wave function, to estimate the energy of the first excited state."

Again I know that when <ψ0lψ(β)> = 0 the variational principle becomes E1≤ <ψlHlψ>/<ψlψ> but does the problem want me to chose a different wavefunction? And if so how to I go about choosing this new wave-function?
 
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The point is to pick a wavefunction which is orthogonal to your first
and use that as a trial to read the first excited energy [again variationally].
The clue is telling you to look at the parity, an even wf. is orthogonal to an odd wf,
so your trial function should be chosen odd.
 
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