What volume of the gas absorbed by the alkali ?

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SUMMARY

The discussion centers on the combustion of a gas mixture consisting of 10 cm³ of methane (CH4) and 10 cm³ of ethane (C2H6) in excess oxygen, followed by the absorption of carbon dioxide (CO2) in aqueous potassium hydroxide (KOH). The balanced equations reveal that the combustion of methane produces 10 cm³ of CO2, while ethane produces 20 cm³ of CO2, resulting in a total of 30 cm³ of CO2 absorbed by KOH. The reaction between CO2 and KOH confirms that the alkaline solution effectively removes CO2 from the gas mixture.

PREREQUISITES
  • Understanding of combustion reactions and stoichiometry
  • Knowledge of chemical equations and balancing techniques
  • Familiarity with the properties of acids and bases, particularly carbon dioxide as an acidic oxide
  • Basic knowledge of gas laws and volume relationships in chemical reactions
NEXT STEPS
  • Study the process of balancing chemical equations, focusing on combustion reactions
  • Learn about the properties and reactions of acidic oxides, specifically carbon dioxide
  • Explore the principles of gas absorption in alkaline solutions, particularly with KOH
  • Investigate the stoichiometric calculations involved in gas reactions and volume conversions
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Chemistry students, educators, and anyone interested in understanding gas reactions, combustion processes, and the interaction of gases with alkaline solutions.

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Homework Statement



A mixture of 10cm^3 of methane and 10cm^3 of ethane was sparked with an excess oxygen . After cooling to room temperature , the residual gas was passed through aqueous potassium hydroxide

What volume of the gas absorbed by the alkali ?

Homework Equations



N/A

The Attempt at a Solution


I have no idea for the solution . Any hint ?
 
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what are the results of 'sparking' methane and ethane with oxygen? i.e. what are the products of combustion?
 
Water and carbon dioxide . I think . So..?
 
And what kind of gas is carbon dioxide? What happens when you pass such a gas through an alkaline solution like KOH?
 
Gokul43201 said:
And what kind of gas is carbon dioxide? What happens when you pass such a gas through an alkaline solution like KOH?


I have no idea . Guide pls .
 
KOH is a base. What do bases (or basic/alkaline solutions) react with?
 
I only know that acid react with base will produce water and salt .
 
Good, then keep in mind that CO2 is an acidic oxide. It is something like an acid, minus the water. It too, will react with a base, forming a salt. The point of this is to recognize that when you pass a gaseous mixture containing CO2 through a solution of KOH, all (or a very large part of) the CO2 will be removed by this reaction.

Write down and balance the equations for the combustion of ethane and methane. How much CO2 is produced from the given quantities?
 
Last edited:
I think the equation is as below :

For methane combustion :
CH4 + O2 ---> CO2 + H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + O2 ---> CO2 + H2O
Since 1 mole of C2H6 : 1 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2Total gas has absorbed is 30 cm^3 ?
Am I correct ?
 
Last edited:
  • #10
You have not balanced the equations. You need to do that before you determine the mole ratios.
 
  • #11
terainfizik said:
I think the equation is as below :

For methane combustion :
CH4 + O2 ---> CO2 + H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + O2 ---> CO2 + H2O
Since 1 mole of C2H6 : 1 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2Total gas has absorbed is 30 cm^3 ?
Am I correct ?
{EDIT}
For methane combustion :
CH4 + 3O2 ---> CO2 + 2H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + 7/2O2 ---> 2CO2 + 3H2O
Since 1 mole of C2H6 : 2 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2 ?

so
total volume is 30cm^3 ?
 
  • #12
Looks good.
 

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