What volume of the gas absorbed by the alkali ?

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Discussion Overview

The discussion revolves around a chemistry homework problem involving the combustion of a mixture of methane and ethane in the presence of excess oxygen, followed by the absorption of carbon dioxide by potassium hydroxide (KOH). Participants explore the products of combustion and the subsequent chemical reactions involved.

Discussion Character

  • Homework-related
  • Technical explanation
  • Mathematical reasoning

Main Points Raised

  • One participant asks for hints regarding the volume of gas absorbed by KOH after the combustion of methane and ethane.
  • Another participant inquires about the products of combustion for methane and ethane when sparked with oxygen.
  • Responses suggest that water and carbon dioxide are the products of combustion.
  • Participants discuss the nature of carbon dioxide as an acidic oxide and its reaction with alkaline solutions like KOH, indicating that CO2 will be absorbed by KOH.
  • One participant proposes the balanced equations for the combustion of methane and ethane, initially stating that 10 cm³ of each gas produces 10 cm³ and 20 cm³ of CO2, respectively.
  • Another participant points out that the combustion equations need to be balanced before determining the mole ratios.
  • A later reply provides the corrected balanced equations for the combustion reactions, leading to a revised calculation of total CO2 produced as 30 cm³.

Areas of Agreement / Disagreement

There is no consensus on the final answer regarding the volume of gas absorbed by KOH, as participants are still discussing the balancing of equations and the implications for the total volume of CO2 produced.

Contextual Notes

Participants have not fully resolved the balancing of combustion equations, which affects the calculations of CO2 produced. The discussion includes assumptions about the completeness of reactions and the behavior of gases in the context of the problem.

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Homework Statement



A mixture of 10cm^3 of methane and 10cm^3 of ethane was sparked with an excess oxygen . After cooling to room temperature , the residual gas was passed through aqueous potassium hydroxide

What volume of the gas absorbed by the alkali ?

Homework Equations



N/A

The Attempt at a Solution


I have no idea for the solution . Any hint ?
 
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what are the results of 'sparking' methane and ethane with oxygen? i.e. what are the products of combustion?
 
Water and carbon dioxide . I think . So..?
 
And what kind of gas is carbon dioxide? What happens when you pass such a gas through an alkaline solution like KOH?
 
Gokul43201 said:
And what kind of gas is carbon dioxide? What happens when you pass such a gas through an alkaline solution like KOH?


I have no idea . Guide pls .
 
KOH is a base. What do bases (or basic/alkaline solutions) react with?
 
I only know that acid react with base will produce water and salt .
 
Good, then keep in mind that CO2 is an acidic oxide. It is something like an acid, minus the water. It too, will react with a base, forming a salt. The point of this is to recognize that when you pass a gaseous mixture containing CO2 through a solution of KOH, all (or a very large part of) the CO2 will be removed by this reaction.

Write down and balance the equations for the combustion of ethane and methane. How much CO2 is produced from the given quantities?
 
Last edited:
I think the equation is as below :

For methane combustion :
CH4 + O2 ---> CO2 + H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + O2 ---> CO2 + H2O
Since 1 mole of C2H6 : 1 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2Total gas has absorbed is 30 cm^3 ?
Am I correct ?
 
Last edited:
  • #10
You have not balanced the equations. You need to do that before you determine the mole ratios.
 
  • #11
terainfizik said:
I think the equation is as below :

For methane combustion :
CH4 + O2 ---> CO2 + H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + O2 ---> CO2 + H2O
Since 1 mole of C2H6 : 1 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2Total gas has absorbed is 30 cm^3 ?
Am I correct ?
{EDIT}
For methane combustion :
CH4 + 3O2 ---> CO2 + 2H2O
Since 1 mole of CH4 : 1 mole of CO2
SO: 10CM^3 CH4 will gives 10 cm^3 CO2

For ethane combustion :
C2H6 + 7/2O2 ---> 2CO2 + 3H2O
Since 1 mole of C2H6 : 2 mole of CO2
So: 10cm^3 C2H6 will gives 20 cm^3 CO2 ?

so
total volume is 30cm^3 ?
 
  • #12
Looks good.
 

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