When do fission products get cooler than fuel?

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SUMMARY

The discussion centers on the thermal and radiotoxicity characteristics of fission products compared to unburned U-235 fuel. It establishes that long-lived fission products, particularly those dominated by Tc-99, are significantly cooler than uranium, with a reduction in radiotoxicity occurring around 200,000 years post-fission. The energy yield from U-235 fission is quantified at 46.4 MeV, with biologic effectiveness reaching approximately 860 MeV over its 710 million year half-life. The conversation highlights the importance of specific activity and energy deposition in assessing the relative danger of fission products versus U-235.

PREREQUISITES
  • Understanding of nuclear fission processes, specifically U-235 and U-238.
  • Familiarity with radioactive decay and half-life concepts.
  • Knowledge of biologic effectiveness and energy deposition in radiation.
  • Experience with data analysis tools, such as spreadsheets, for calculating activity and energy deposition.
NEXT STEPS
  • Research the decay chains of long-lived fission products, focusing on Tc-99 and Sr-90.
  • Learn about the transmutation processes of uranium isotopes, particularly 236Np and 239Pu.
  • Examine the plots of radioactive decay and radiotoxicity available online to understand long-term radiological safety.
  • Study advanced nuclear energy systems and their methods for transmuting long-lived fission products.
USEFUL FOR

Nuclear engineers, radiation safety professionals, and researchers in nuclear physics will benefit from this discussion, particularly those focused on the long-term management of nuclear waste and radiotoxicity assessment.

snorkack
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Main nuclear fuel is U-235.
Actinium series to stable Pb-207 includes 7 alpha and 4 beta decays. Total energy yield 46,4 MeV.
In the main branch, the 4 beta decays carry around 3 MeV energy. Meaning the alpha decays are about 43 MeV... and they have high biologic effectiveness, around 20. Meaning U-235 does about 860 MeV worth of damage in its 710 million year half-life... about 1200 keV per million years.
When U-235 is fissioned, some daughters are stable. Others are hot but short-lived and promptly decay to stable daughters in 100 years or less half-life
This leaves 7 or so long lived fission products. But even these are beta active... limited total energy, limited biologic effectiveness and limited yield.

Are long lived fission products actually hotter than the original unburned U-235+daughter chain?
 
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What do you mean by 'hotter' and 'cooler'? Are you referring to their literal temperature?
 
Drakkith said:
What do you mean by 'hotter' and 'cooler'? Are you referring to their literal temperature?
No, as can be seen from my arguments.
"Hotter" as in "more biologically damaging radiation per unit time".
 
One could use a spreadsheet and look at the individual and sum of activity (decays/time) and energy deposition (activity * energy/decay) for the longest living fission products, and perhaps the medium fission products, and compare to the activity and energy deposition of 235U. Furthermore, one may consider the specific activity, e.g., per gram of material.

https://en.wikipedia.org/wiki/Long-lived_fission_product#The_7_long-lived_fission_products

However, consider that while 235U is the principal fuel, some fission occurs in 238U from fast neutrons, and perhaps more importantly, both nuclides are transmuted by neutron capture to transuranic radioisotopes, 236Np and 239Pu, respectively, which can also transmute to 237Np and 240Pu, respectively, and so on.

See also, the plot of activities of FP and TU radionuclides:
https://www.titech.ac.jp/english/news/2017/039701

On a related subject matter

Transmutation of long-lived fission products in an advanced nuclear energy system​

https://www.nature.com/articles/s41598-022-06344-y
 
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Looks like the long lived fission products, dominated by Tc-99, are 1000 times cooler than uranium, and fission products dominated by Sr-90 get cooler than uranium in 300 years or so... except for the transuranium elements, due to which the radioactivity lasts closer to 10 000 years.
 
If you are looking for a general answer of when spent fuel is less radiotoxic than natural uranium ore, there are several plots that you can find on the internet.

For example, this plot shows it will occur in about 200,000 years.
https://en.wikipedia.org/wiki/File:Spent_nuclear_fuel_decay_sievert.jpg

There are other plots you can see by doing a search on "image radioactive decay radiotoxicity"
 
snorkack said:
No, as can be seen from my arguments.
"Hotter" as in "more biologically damaging radiation per unit time".
FYI, I couldn't "see" that from your OP, @snorkack, but are you able to share the context for your question? Radiation toxicity depends on many factors such that a 'cooler' element may be more lethal than a 'hotter' one through the circumstances of contact.
 

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