Which Reaction Has the Highest Kp Value?

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SUMMARY

The discussion centers on determining which reaction has the highest equilibrium constant (Kp) value among four thermal decomposition reactions of carbonates: MgCO3, CaCO3, SrCO3, and BaCO3. Participants conclude that the Kp value is primarily influenced by the ease of thermal decomposition of the carbonates. The consensus suggests that MgCO3(s) decomposes most readily, resulting in the highest Kp value. This conclusion is based on the understanding that Kp correlates with the partial pressure of CO2 produced during decomposition.

PREREQUISITES
  • Understanding of chemical equilibrium and Kp values
  • Knowledge of thermal decomposition reactions
  • Familiarity with the properties of alkaline earth metal carbonates
  • Basic grasp of gas laws and partial pressures
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  • Research the thermal decomposition characteristics of alkaline earth metal carbonates
  • Study the relationship between Kp and reaction spontaneity
  • Learn about the factors affecting Kp values in chemical reactions
  • Explore the concept of Le Chatelier's principle in equilibrium systems
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Homework Statement


Which has the max. value of KP-
a)MgCO3(s) --> MgO(s)+CO2(g)
b)CaCO3(s) --> CaO(s)+CO2(g)
c)SrCO3(s) --> SrO(s)+CO2(g)
d)BaCO3(s) --> BaO(s)+CO2(g)

Homework Equations





The Attempt at a Solution



I don't understand how we could determine which has the max. Kp because in all the equations Kp=PCO2. What other factors should i look into?

Thanks!
 
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Perhaps it asks about the ease of the thermal decomposition?
 
Borek said:
Perhaps it asks about the ease of the thermal decomposition?

Then i guess the answer is a). Right? :smile:
 
If I will answer yes or no I will do your homework.
 
Borek said:
If I will answer yes or no I will do your homework.

It isn't a homework question anyway, it is a question from a test i gave a few days ago.
But i am sure about the answer.
 

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