Why (and how) do foods stick to a pan?

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SUMMARY

Foods high in protein, particularly low-fat options like lean white fish and egg whites, are prone to sticking to non-coated metal surfaces. To mitigate this, it is essential to preheat the pan, add oil or butter, and allow it to reach the appropriate temperature before introducing the food. Key factors influencing food adhesion include the material properties of the pan, surface state characteristics, and physical phenomena such as lubrication and intermolecular forces. Understanding these elements can significantly enhance cooking techniques and prevent sticking.

PREREQUISITES
  • Understanding of protein composition in foods
  • Knowledge of cooking techniques involving oil and fat
  • Familiarity with material properties of cookware
  • Basic principles of heat transfer and surface interactions
NEXT STEPS
  • Research the effects of pan material on cooking performance
  • Learn about the role of surface roughness in food adhesion
  • Explore the science of lubrication in cooking
  • Investigate the impact of temperature on food texture and sticking
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Culinary enthusiasts, chefs, food scientists, and anyone interested in improving cooking techniques and understanding the science behind food adhesion.

Ganesh Ujwal
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We all (sooner or later) have noticed that foods relatively high in protein (especially those low in fat) are very prone to sticking to a pan, or in general to any non-specially-coated metal surface. For example really lean white fish, which is almost all protein, is one of those devils which will always want to stick. Likewise, egg whites can stick. To some extent, almost any food that doesn't have a generous amount of easy-rendering fat seems to stick, but higher protein is more sticky.

To counteract this tendency, one learns to compensate by putting some kind of fat (usually oil or butter) into the pan in advance of the food. Most people seem to get the best result by preheating the dry pan some, then adding the oil, letting it get up to temperature, then adding the food.

I was just trying to ask myself what would be a simple and general sketch of what is going on on the surface of a pan when sticking takes place, and in particular:

1) what features of a material (density, chemical composition, elasticity, specific heat,etc.)

2) and of the state of the surface (temperature, roughness, etc.)

have a dominant role in the physics of such a system.

3) Which phenomena (lubrication, intermolecular forces, order-disorder phase-transitions, etc.) are more likely to be responsible for what we experience in our every-day life.
 
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Food sticks when cooking when there are scratches in the pan and the food has a fluid(ish) stage followed by a more solid stage (burned food sticks).
What makes something sticky is actually quite complicated, and with food, the situation is changing due to the heating.
 

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