Why can sulphur lose 6 electrons while magnesium can't gain 6?

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SUMMARY

Sulphur can exhibit oxidation states of +6 or -2, while magnesium consistently forms a +2 ion due to differences in electronegativity and electron affinity. Magnesium's lower electronegativity makes it less capable of attracting additional electrons, resulting in its stable +2 ionic form. In contrast, sulphur's ability to lose up to six electrons is evident in compounds like H2SO4, although it typically forms a -2 ion in ionic compounds. Oxidation numbers serve as a bookkeeping method rather than reflecting actual atomic charges.

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  • Understanding of oxidation states and their significance in chemistry
  • Knowledge of electronegativity and its role in chemical bonding
  • Familiarity with ionic compounds and their formation
  • Basic principles of electron configuration and the octet rule
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  • Research the concept of electronegativity and its impact on chemical reactivity
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dontdisturbmycircles
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Hello,

I am fighting with a problem from grade 11 chem right now.

The problem is why when sulphur bonds to other atoms, its ion charge often becomes 6+ or 2- while magnesium will always form an ion of charge 2+.

I think I have an answer but am not sure. Is it because magnesium has a lower electronegativity and is less able/willing to attract extra elections? but then I have the paradox of why sulphur would be willing to lose 6(!) electrons with such a high desire to fill its last two orbitals and complete its octet (high electronegativity). :mad:
 
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Sulfur never loses 6 electrons to form a stable ionic compound. Sulfur can however have a +6 oxidation state in compounds such as H2SO4. Realize that oxidation numbers are simply part of a "bookeeping" method devised by humans to keep track of which chemical species are being oxidized and reduced. Oxidation numbers do not represent the actual charge on an atom.

With regards to ionic compounds, Mg is most stable as Mg+2 and S as S-2.
 

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