Why do fats contain the most energy per gram?

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SUMMARY

Fats contain the most energy per gram due to their high caloric density, providing approximately 9 kcal per gram compared to carbohydrates and proteins, which offer about 4 kcal per gram. The human body stores around 100,000 kcal in lipid reserves, enabling survival without food for 30-40 days, significantly surpassing the 600 kcal available from glycogen. This efficiency is crucial for energy storage, particularly in hibernating animals and migrating birds, where fats serve as the primary energy source. The compact nature of lipids prevents excessive weight gain that would occur if glycogen were the main energy reserve.

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hi everyone

I was wondering why do fats contrain the most energy per gram?
 
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http://www.elmhurst.edu/~chm/vchembook/images/590metabolism.gif

he free glucose in the blood provides only a 40 kcal energy reserve -- only enough to maintain body functions for a few minutes.

Glycogen remaining stored in the liver and muscles after an overnight fast, amounts to about 600 kcal energy. Glycogen reserves can maintain body functions for about one day without new inputs of food. Protein (mostly in muscle) contains a substantial energy reserve of about 25,000 kcal.

Finally, lipid reserves containing 100,000 kcal of energy can maintain human body functions without food for 30-40 days with sufficient water. Lipids or fats represent about 24 pounds of the body weight in a 154 pound male. Lipids provide the sole source of energy in hibernating animals and migrating birds. Fortunately, lipids are more compact and contain more energy per gram than glycogen, otherwise body weight would increase approximately 110 pounds if glycogen were to replace fat as the energy

http://www.elmhurst.edu/~chm/vchembook/620fattyacid.html
 
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