Why does arsenic sublimate, while gallium melts?

Click For Summary
SUMMARY

This discussion analyzes the physical properties of arsenic and gallium, focusing on their phase transitions. Arsenic sublimates due to its strong covalent bonds, which require significant energy to break, while gallium melts at a lower temperature due to its noncovalent interactions that allow for easier atomic movement. The conversation emphasizes the relationship between melting and boiling points and the nature of molecular bonds, highlighting the importance of understanding these properties in materials science.

PREREQUISITES
  • Understanding of phase transitions in materials science
  • Knowledge of covalent and noncovalent bonding
  • Familiarity with entropy and enthalpy concepts
  • Basic principles of molecular interactions
NEXT STEPS
  • Research the properties of covalent versus noncovalent bonds
  • Learn about phase diagrams and their implications in materials science
  • Study the concepts of entropy and enthalpy in detail
  • Explore the melting and boiling points of various elements and compounds
USEFUL FOR

Chemists, materials scientists, and students studying physical chemistry who are interested in the behavior of substances during phase transitions.

Tiiba
Messages
53
Reaction score
0
What does it tell you about a substance? A height melting and boiling point means that the molecules hold together strongly, as in tungsten. A low melting point, as in hydrogen, means they're kinda loose. But what does the distance between them tell you?

Something something entropy yadda yadda enthalpy. But what?
 
Chemistry news on Phys.org
I'd say it says something about covalent or noncovalent nature of the bonds.
If the bonds are covalent and directional, then break them enough as to break down the long range order and you've broken mostly all of them.
If bonds are noncovalent, nearest neighbour interactions, you can break a few of them and allow atoms to slide from one nearest neighbour to another while still being bound in the liquid.
 

Similar threads

  • · Replies 8 ·
Replies
8
Views
6K
  • · Replies 13 ·
Replies
13
Views
2K
  • · Replies 6 ·
Replies
6
Views
9K
Replies
4
Views
3K
  • · Replies 1 ·
Replies
1
Views
4K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 3 ·
Replies
3
Views
16K
  • · Replies 7 ·
Replies
7
Views
4K
Replies
5
Views
5K
Replies
17
Views
5K