Why does ferrous iron make 6 covalent bonds?

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SUMMARY

Ferrous iron (Fe²⁺) can form six covalent bonds due to its ability to utilize d-orbitals for bonding, allowing it to achieve a stable electronic configuration. This bonding behavior is particularly relevant in biochemical processes such as bilirubin metabolism, where red blood cells produce hemin in its ferrous state. The discussion highlights the importance of understanding crystal field theory in explaining the bonding characteristics of ferrous iron, despite its limited focus on covalent bonds.

PREREQUISITES
  • Understanding of crystal field theory
  • Knowledge of electron configurations and subshells
  • Familiarity with the oxidation states of iron (Fe²⁺ and Fe³⁺)
  • Basic concepts of biochemical pathways, particularly bilirubin metabolism
NEXT STEPS
  • Research the implications of crystal field theory on transition metal bonding
  • Study the role of ferrous iron in biological systems
  • Explore the differences between ferrous and ferric iron in metabolic processes
  • Investigate the structure and function of hemin in red blood cells
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Students and professionals in biochemistry, inorganic chemistry, and molecular biology who seek to understand the bonding properties of transition metals and their biological significance.

sameeralord
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Hello everyone,

Is their simple reason for this. Like how there must be 8 electrons in outer shell,I know that is very basic and probably not applicable, or is this something to do with sub shells etc.

Also in billirubin metabolism. Why do red blood cells produce hemin which is iron in ferrous state. Normally in body shouldn't the iron be in in ferric form to function.

Thanks :smile:
 
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