Why Does Water Behave Anomalously?

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SUMMARY

The anomalous behavior of water is primarily attributed to its unique hydrogen bonding, which causes water to expand upon freezing and exhibit a maximum density at 4°C. As the temperature decreases, water molecules slow down, leading to increased density until 4°C, after which crystallization occurs, resulting in decreased density and increased volume. This behavior is distinct from most other liquids, which typically contract upon cooling. The discussion also raises questions about the potential for altering the temperature range of this phenomenon.

PREREQUISITES
  • Understanding of hydrogen bonding in molecular chemistry
  • Basic knowledge of thermodynamics and phase transitions
  • Familiarity with the molecular structure of water (H2O)
  • Concept of density and its relation to temperature changes
NEXT STEPS
  • Research the effects of pressure on the phase behavior of water
  • Explore the concept of supercooling and its implications for water's properties
  • Investigate other substances that exhibit anomalous behavior similar to water
  • Study the implications of water's unique properties on ecological and biological systems
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Students and professionals in chemistry, environmental science, and physics, as well as anyone interested in the unique properties of water and their implications in various scientific fields.

djsourabh
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What is the exact scientific reason behind anamalous behavour of water?
Can the temperature range at which this happens be changed?
do any other substances also behave anamalously?
 
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mmm...what's anomalous?
 
No, no, the OP clearly said anamalous, whatever that is.
 
He did say anamalous but that was probably just a typing error. He meant to write anomalous.
 
He wrote anamalous three times, it is not a typo.

To OP: please elaborate. In most cases water behaves as every other liquid. Sometimes it doesn't, but you need to explain what you mean if you want to get any help.

Besides, it looks like a HW question to me...
 
Sorry for typing mistake.
I meant ' anomalous' only.
It's not a HW question.
 
So what are you talking about Sourabh?
Large specific heat, expansion while freezing, inertness, or something else?
 
The weird behaviour at 4 C to 0 C .
 
Well, water is composed of three atoms two hydrogen and one oxygen. So a molecule looks likes this:
attachment.php?attachmentid=61616&stc=1&d=1378700879.gif

-When the temperature decreases the molecules start slowing down.
-This causes the volume to decrease and density to increase until 4°C while its still in liquid state.
-After this the molecules start crystallizing in a cage like structure by hydrogen bonding. Hydrogen bonding is a weak molecular interaction between the oxygen of one molecule and Hydrogen of another.
-In the crystallization process the density decreases and volume increases as the H-bonds push molecules apart to maintain a stable crystal lattice.
-The differences can be seen in this image [left is liquid and right is ice]:
320px-Liquid-water-and-ice.png

The temperature and pressure relationship of water is given by:
attachment.php?attachmentid=61615&stc=1&d=1378699692.gif
 

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  • #10
Bonds, bonds - Hydrogen bonds!
 
  • #11
ModusPwnd said:
Bonds, bonds - Hydrogen bonds!

Bond... hydrogen bond.
Shaken, not stirred.
 
  • #12
Drakkith said:
Bond... hydrogen bond.
Shaken, not stirred.
Nooo, supercool it and then shake it! The drink shall turn to Ice cream...
https://www.youtube.com/watch?v=DpiUZI_3o8s

The actual drink is a Vesper martini, it went like this:
"A dry martini," Bond said. "One. In a deep champagne goblet."
"Oui, monsieur."
"Just a moment. Three measures of Gordon's, one of vodka, half a measure of Kina Lillet. Shake it very well until it's ice-cold, then add a large thin slice of lemon peel. Got it?"
 
  • #13
Enigman said:
Well, water is composed of three atoms two hydrogen and one oxygen. So a molecule looks likes this:
attachment.php?attachmentid=61616&stc=1&d=1378700879.gif

-When the temperature decreases the molecules start slowing down.
-This causes the volume to decrease and density to increase until 4°C while its still in liquid state.
-After this the molecules start crystallizing in a cage like structure by hydrogen bonding. Hydrogen bonding is a weak molecular interaction between the oxygen of one molecule and Hydrogen of another.
-In the crystallization process the density decreases and volume increases as the H-bonds push molecules apart to maintain a stable crystal lattice.
-The differences can be seen in this image [left is liquid and right is ice]:
320px-Liquid-water-and-ice.png

The temperature and pressure relationship of water is given by:
attachment.php?attachmentid=61615&stc=1&d=1378699692.gif

Thank you for such agood description.
My next query is "can the temperature range at which this phenomena occurs be changed by any means?"
 

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